A novel polymerizable imidazole derivative for blue light-emitting material

被引:29
|
作者
Fang, Zhangjian
Wang, Shimin [1 ]
Zhao, Lei
Xu, Zuxun
Ren, Jun
Wang, Xianbao
Yang, Qiongfeng
机构
[1] Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
[2] Wuhan Univ Sci & Technol, Key Lab Refractories Mat Hubei Prov, Wuhan 430081, Peoples R China
基金
中国国家自然科学基金;
关键词
imidazole derivative; luminescent material; photoluminescence; thermal stability;
D O I
10.1016/j.matlet.2007.03.038
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel imidazole derivative, 2-(4-(2,5-dibutoxy-4-vinyistyryl)phenyl)-4,5-diphenyl-1H-imidazole) (VPDPI), as optoclectronic material was designed and synthesized by heck coupling reaction. The structure, thermal analysis and photoluminescence (PL) properties were investigated. The results indicate that the organic compound has good PL property. The emission peak of VPDPI is in the blue regions (465 tun), and the luminescence quantum yield is 0.61 in ethanol, which show that the compound emits blue light and is a desirable blue-emitting photoluminescence material. Also the organic compound shows better thermal stability due to the molecular structure introduced by imidazole heterocyle. The compound can be polymerized for the design of novel and efficient organic optoelectronic materials. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:4803 / 4806
页数:4
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