Redox Gradations in Ruthenium Porphycene Complexes and the Porphyrin Analogs: Axial and Macrocyclic Ligand Effects

被引：13

作者：

Okawara, Toru ^{[1
]}

Abe, Masaaki ^{[1
]}

Shimakoshi, Hisashi ^{[1
]}

Hisaeda, Yoshio ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190935, Japan

来源：

CHEMISTRY LETTERS | 2008年 / 37卷 / 09期

关键词：

D O I：

10.1246/cl.2008.906

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports synthesis and electrochemistry of six-coordinate ruthenium porphyrin isomers including six novel porphycene complexes with substituted pyridines in the axial positions, in which redox potential control of reversible Ru-II/R-III processes is successfully achieved over a 0.7-V potential region by varying the axial ligands and tetrapyrrole ligand structure and substituents.

引用

页码：906 / 907

页数：2

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