An Iron-Catalyzed Direct Approach to Amides from Benzyl Azides via C-C Bond Cleavage

被引：1
|
作者：
Ou, Yang [1 ]
Qin, Chong [1 ]
Song, Song [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2015年 / 47卷 / 19期
基金：
中国国家自然科学基金;
关键词：
C-C bond cleavage; azides; amides; rearrangement; H AZIDATION; SCHMIDT REACTION; DIRECT TRANSFORMATION; HYDROXYALKYL AZIDES; COUPLING REAGENTS; ROOM-TEMPERATURE; ALKYL AZIDES; NITROGENATION; KETONES; ARYL;
D O I：
10.1055/s-0034-1380222
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel iron-catalyzed transformation of benzyl azides to give the corresponding amides via C-C bond cleavage under mild reaction conditions is developed. This method provides a new synthetic tool for the construction of amides and the opportunity to accomplish C-C functionalization under mild conditions.
引用
收藏
页码：2971 / 2975
页数：5
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