catena-Poly[[bis(cis-1-tert-butyltetrazole-κN4)copper(II)]-di-μ-chloro]

被引：25
|
作者：
Ivashkevich, DO [1 ]
Degtyarik, MM [1 ]
Gaponik, PN [1 ]
Lyakhov, AS [1 ]
机构：
[1] Belarusian State Univ, Physicochem Res Inst, Minsk 220050, BELARUS
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷
关键词：
D O I：
10.1107/S0108270102004754
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title polymeric compound, [CuCl2(C5H10N4)(2)](n), is the first structurally characterized complex with a bulky 1-alkyl-tetrazole ligand. The coordination polyhedron of the Cu atom is an elongated octahedron. The equatorial positions of the octahedron are occupied by the two Cl atoms, with Cu-Cl distances of 2.2920 (8) and 2.2796 (9) Angstrom, and by the two N-4 atoms of the tetrazole ligands, with Cu-N distances of 2.023 (2) and 2.039 (2) Angstrom. Two symmetry-related Cl atoms occupy the axial positions, at distances of 2.8244 (8) and 3.0174 (8) Angstrom from the Cu atom. The [CuCl2(C5H10N4)(2)] units form infinite chains extended along the b axis, linked together only by van der Waals interactions. The skeleton of each chain consists of Cu and Cl atoms.
引用
收藏
页码：m288 / m289
页数：2
相关论文
共 50 条
  • [21] catena-Poly[[bis(4-aminopyrimidine-κN1)-copper(II)]-di-μ-dicyanamido-κ4N1:N3]
    Kozísek, J
    Díaz, JG
    Fronc, M
    Svoboda, I
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1150 - M1152
  • [22] Crystal structure of catena-poly[cis-bis(1-phenyltetrazole-κN4)-di(μ-chloro)copper(II)], Cu(C7H6N4)2Cl2
    Liu, Xiang-Yun
    Zhang, Yan-Hua
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (02): : 293 - 294
  • [23] catena-Poly[[bis(quinoxaline-κN)-cobalt(II)]-di-μ-dicyanamido-κ2N1:N5] and catena-poly[[bis(quinoxaline-κN)copper(II)]-di-μ-dicyanamido-κ2N1:N5]
    Luo, J
    Liu, BS
    Zhou, XG
    Weng, LH
    Li, YR
    Wu, HX
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : M520 - M522
  • [24] catena-Poly[bis(4-aminopyridinium) [[diaquamanganese(II)]-di-μ-chlorido] dichloride]
    Zgolli, Donia Zaouali
    Boughzala, Habib
    Driss, Ahmed
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M921 - U933
  • [25] catena-poly[[aqua(pyridine N-oxide-κO)-cadmium(II)]-di-μ-chloro]
    Englert, U
    Schiffers, S
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M295 - M296
  • [26] catena-poly[mercury(II)-di-μ-chloro-μ-pyridazine-κ2N:N′]
    Nockemann, P
    Meyer, G
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M751 - M752
  • [27] catena-poly[[bis(N,N-dimethylformamide)-cobalt(II)]-di-μ-1,5-dicyanamido]
    Tong, ML
    Zhou, AJ
    Hu, S
    Chen, XM
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 : M405 - M407
  • [28] catena-Poly[[dipyridylcopper(II)]-di-μ-thiocyanato]
    Chen, G
    Bai, ZP
    Qu, SJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : M2718 - M2719
  • [29] catena-Poly[cadmium(II)-di-μ-chloro-μ-4-1H-pyridone-κO:κO]
    Englert, U
    Schiffers, S
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M194 - M195
  • [30] catena-poly[di-μ2-chloro(1,10-phenanthroline)cadmium(II)]
    Chen, HB
    Zhou, ZH
    Wan, HL
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M845 - M846
12345