Synthesis, structure and electric properties of a novel solid solution system: (1-x)Pb(Zr0.52Ti0.48)O3-xBi(Zn2/3Nb1/3)O3

被引：2

作者：

Liu, Zenghui ^{[1
,2
,3
,4
]}

Wu, Hua ^{[1
,2
,5
]}

Ren, Wei ^{[3
,4
]}

Ye, Zuo-Guang ^{[1
,2
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

[2] Simon Fraser Univ, 4D LABS, Burnaby, BC V5A 1S6, Canada

[3] Xi An Jiao Tong Univ, Minist Educ, Key Lab, Elect Mat Res Lab, Xian, Shaanxi, Peoples R China

[4] Xi An Jiao Tong Univ, Int Ctr Dielect Res, Xian, Shaanxi, Peoples R China

[5] Donghua Univ, Dept Appl Phys, Shanghai, Peoples R China

来源：

FERROELECTRICS | 2018年 / 533卷 / 01期

基金：

中国国家自然科学基金; 加拿大自然科学与工程研究理事会;

关键词：

PZT; Bi(Zn2; 3Nb1; 3)O-3; ferroelectric and piezoelectric properties; complex perovskite solid solution; FERROELECTRIC CERAMICS; PHASE;

D O I：

10.1080/00150193.2018.1470839

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ceramics of a novel solid solution system, (1-x)Pb(Zr0.52Ti0.48)O-3-xBi(Zn2/3Nb1/3)O-3 [(1-x)PZT-xBZN], with compositions near the morphotropic phase boundary (MPB), are synthesized by solid-state reaction method and investigated by X-ray diffraction, dielectric spectroscopy, and ferroelectric and piezoelectric measurements. It is found that the increasing amount of Bi(Zn2/3Nb1/3)O-3 (BZN) changes the structure of this system from the tetragonal symmetry to the MPB. The remnant polarization, coercive field and electromechanical properties are significantly enhanced compared with pure PZT ceramics, which is correlated with the MPB feature of the (1-x)PZT-xBZN system. With the increase of BZN content, a gradually diffuse phase transformation with monotonically decreasing Curie temperature and increasing dielectric loss is found.

引用

页码：183 / 191

页数：9

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