Quadrupole interactions at 57Fe and 119Sn in 3d-metal antimonides

被引：3
|
作者：
Tkachenka, T. M. [1 ]
Virchenko, V. A. [1 ]
机构：
[1] Natl Acad Sci Belarus, Inst Solid State & Semicond Phys, Minsk, BELARUS
来源：
HYPERFINE INTERACTIONS | 2006年 / 168卷 / 1-3期
关键词：
3d-metal antimonide; NiAs-type of crystal structure; octahedral site; trigonal-bipyramidal site; stoichiometric composition; concentration excess; property-composition correlation; Mossbauer effect; quadrupole splitting of Mossbauer spectrum;
D O I：
10.1007/s10751-006-9392-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1-y Fe (y) )Sb solid solution have been studied by the Mossbauer effect method at Fe-57 and Sn-119. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of Sn-119. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of Sn-119 in 3d-metal antimonides in the 0 <= x <= 0.1 concentration range can be used to determine x - the concentration of transition metal excess relative to the stoichiometric composition.
引用
收藏
页码：1047 / 1050
页数：4
相关论文
共 50 条
  • [41] THE QUADRUPOLE INTERACTION ON SN-119 NUCLEI IN TRANSITION-METAL ANTIMONIDES OF EQUIATOMIC COMPOSITION
    VASILIEV, EA
    VIRCHENKO, VA
    TKACHENKO, TM
    SHABLOVSKII, AV
    DOKLADY AKADEMII NAUK BELARUSI, 1985, 29 (11): : 985 - 986
  • [42] 大厂辉锑锡铅矿的119Sn和57Fe穆斯堡尔谱研究
    吴功保
    黄民智
    岩石矿物学杂志, 1986, (04) : 346 - 352
  • [43] Characterization of Ag-Ge-Se bulk glasses by means of Mossbauer effect on 57Fe and 119Sn atomic nuclei.
    Arcondo, B.
    Urefia, M. A.
    Conde Garrido, J. M.
    Rocca, J. A.
    Fontana, M.
    INTERNATIONAL CONFERENCE ON THE APPLICATIONS OF THE MOSSBAUER EFFECT (ICAME 2009), 2010, 217
  • [44] Mixed phase in cubic and hexagonal HoMn2 111Cd PAC and 119Sn, 57Fe Mossbauer studies
    Cottenier, S
    Meersschaut, J
    Demuynck, S
    Swinnen, B
    Rots, M
    Krop, K
    Marzec, J
    Zukrowski, J
    Przewoznik, J
    Japa, E
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1998, 177 : 1083 - 1084
  • [45] Enhanced 119Sn Moessbauer quadrupole interactions below the magnetic phase transition of UPt2Sn
    Universitaet zu Koeln, Koeln, Germany
    Physica B: Condensed Matter, 1997, 230-232 : 95 - 97
  • [46] QUADRUPOLE INTERACTIONS AT FE-57 IN TE METAL
    VERMA, HC
    RAO, GN
    PHYSICAL REVIEW B, 1980, 22 (07): : 3152 - 3156
  • [47] QUADRUPOLE INTERACTIONS AT FE-57 IN TITANIUM METAL
    KHAN, DC
    NAIR, NV
    HYPERFINE INTERACTIONS, 1986, 28 (1-4): : 1001 - 1004
  • [48] Mossbauer Characterization of Electronic States and Local Surroundings of 57Fe and 119Sn in Ca-Substituted Lutetium Orthoferrites Lu1-xCaxFe0.997Sn0.003O3
    Mezhuev, E. M.
    Afanasov, M. I.
    Larionov, D. S.
    Korolenko, M. V.
    Fabrichnyi, P. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (12) : 1610 - 1616
  • [49] HYPERFINE INTERACTIONS AT FE-57 AND SN-119 NUCLEI IN MNSB
    BLAAUW, C
    MACKAY, GR
    LEIPER, W
    JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1977, 10 (24): : 5071 - 5081
  • [50] Mössbauer Characterization of Electronic States and Local Surroundings of 57Fe and 119Sn in Ca-Substituted Lutetium Orthoferrites Lu1 – xCaxFe0.997Sn0.003O3
    E. M. Mezhuev
    M. I. Afanasov
    D. S. Larionov
    M. V. Korolenko
    P. B. Fabrichnyi
    Russian Journal of Inorganic Chemistry, 2018, 63 : 1610 - 1616
12345