Quadrupole interactions at 57Fe and 119Sn in 3d-metal antimonides

被引：3
|
作者：
Tkachenka, T. M. [1 ]
Virchenko, V. A. [1 ]
机构：
[1] Natl Acad Sci Belarus, Inst Solid State & Semicond Phys, Minsk, BELARUS
来源：
HYPERFINE INTERACTIONS | 2006年 / 168卷 / 1-3期
关键词：
3d-metal antimonide; NiAs-type of crystal structure; octahedral site; trigonal-bipyramidal site; stoichiometric composition; concentration excess; property-composition correlation; Mossbauer effect; quadrupole splitting of Mossbauer spectrum;
D O I：
10.1007/s10751-006-9392-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1-y Fe (y) )Sb solid solution have been studied by the Mossbauer effect method at Fe-57 and Sn-119. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of Sn-119. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of Sn-119 in 3d-metal antimonides in the 0 <= x <= 0.1 concentration range can be used to determine x - the concentration of transition metal excess relative to the stoichiometric composition.
引用
收藏
页码：1047 / 1050
页数：4
相关论文
共 50 条
  • [1] Quadrupole interactions at 57Fe and 119Sn in 3d-metal antimonides
    T. M. Tkachenka
    V. A. Virchenko
    Hyperfine Interactions, 2006, 168 : 1047 - 1050
  • [2] Studies on 119Sn and 57Fe Mossbauer Spectra of Stannite
    江嘉济
    黄文英
    岩石矿物学杂志, 1992, (03) : 267 - 272
  • [3] Hyperfine magnetic interactions in iron antimonide on 57Fe, 121Sb, and 119Sn
    Thomas, M.F.
    Tkachenko, T.M.
    Fizika Nizkikh Temperatur, 2013, 39 (12): : 1346 - 1349
  • [4] Hyperfine magnetic interactions in iron antimonide on 57Fe, 121Sb, and 119Sn
    Thomas, M. F.
    Tkachenko, T. M.
    LOW TEMPERATURE PHYSICS, 2013, 39 (12) : 1048 - 1050
  • [5] 119Sn and 57Fe Mossbauer study of highly conductive vanadate glass
    Nishida, Tetsuaki
    Fujita, Yuki
    Shiba, Sachiya
    Masuda, Sayaka
    Yamaguchi, Naomi
    Izumi, Tomoka
    Kubuki, Shiro
    Oka, Nobuto
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (09) : 8847 - 8854
  • [6] 57Fe and 119Sn Miissbauer Effect Study of Fe-Sn-B Amorphous Alloys
    Miglierini, M.
    Rusakov, V. S.
    MOSSBAUER SPECTROSCOPY IN MATERIALS SCIENCE - 2010, 2010, 1258 : 29 - +
  • [7] Complementary 57Fe and 119Sn Mossbauer study of mechanochemical redox reaction
    Sepelak, V.
    Isfahani, M. J. Nasr
    Myndyk, M.
    Ghafari, M.
    Feldhoff, A.
    Becker, K. D.
    HYPERFINE INTERACTIONS, 2011, 202 (1-3): : 39 - 46
  • [8] Disordered nanocrystalline Fe-Sn alloys -: 57Fe and 119Sn Mossbauer spectroscopy study
    Yelsukov, EP
    Voronina, EV
    Konygin, GN
    Godovikov, SK
    Fomin, VM
    MOSSBAUER SPECTROSCOPY IN MATERIALS SCIENCE, 1999, 66 : 283 - 290
  • [9] Nonconservation of spatial parity in Moessbauer transitions at 57Fe and 119Sn nuclei
    Inzhechik, L.V.
    Rogozev, B.I.
    Khlebnikov, A.S.
    Tsinoev, V.G.
    Bulletin of the Academy of Sciences of the U.S.S.R. Physical series, 1988, 52 (09): : 87 - 90
  • [10] The 119Sn and 57Fe Mossbauer study of layered Sn-Fe-Sn system subjected to thermal annealing
    Rusakov, V.S.
    Kadyrzhanov, K.K.
    Korshiev, B.O.
    Turkebaev, T.E.
    Vereschak, M.F.
    Poverkhnost Rentgenovskie Sinkhronnye i Nejtronnye Issledovaniya, 2005, (01): : 60 - 68
12345