Crystal structures of (Et4N)2C2S6, (Et4N)2C2S5, (Et4N)2CS4, (Et4N)HCS3, (Et4N)2CS3•2H2O and (Et4N)2CS4-y•yH2O (y=0.69).

被引：1
|
作者：
Bernhardt, Eduard [1 ]
机构：
[1] Berg Univ Wuppertal, Anorgan Chem, Fak Math & Nat Wissensch, Gaussstr 20, D-42119 Wuppertal, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2021年 / 647卷 / 07期
关键词：
Thiocarbonate; Perthiocarbonate; Tetraethylammonium; ELECTROCHEMICAL PREPARATION; TRITHIOCARBONATE; PERTHIOCARBONATE; MONOHYDRATE; COMPLEXES; ADDUCT; ANION;
D O I：
10.1002/zaac.202100001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structures of (Et4N)(2)C2S6, (Et4N)(2)C2S5, (Et4N)(2)CS4, (Et4N)HCS3, (Et4N)(2)CS3 center dot 2H(2)O and (Et4N)(2)CS4-y center dot yH(2)O (y=0.69) were determined by single-crystal X-ray diffraction analysis at 150 K. For the first time, salts with the C2S52- and HCS3- anions could be synthesized.
引用
收藏
页码：777 / 782
页数：6
相关论文
共 50 条
  • [41] The investigation on the band structures of the anions of Mo2S4(i-mnt)2(Et4N)2 and (Et4N)3K[Mo2S4(i-mnt)2]2[i-mnt=S2C(CN)2-] complexes
    Cai, SH
    Chen, Z
    Sun, FX
    Gao, XC
    Lu, SF
    ACTA CHIMICA SINICA, 1998, 56 (11) : 1117 - 1122
  • [42] Synthesis and thermal analysis of tetraethylammonium bromochlorocobaltates(II) [Et4N]2[CoBrnCl4-n]
    Styczen, Emilia
    Warnke, Zygmunt
    Wyrzykowski, Dariusz
    THERMOCHIMICA ACTA, 2007, 454 (02) : 84 - 89
  • [43] Syntheses and crystal structures of the homoleptic [Et4N][M(SC6H4Me-p)4] (M = Ga, In) and [Et4N][Ga(SePh)4]
    Han, Yan-Gong
    Xu, Chao
    Duan, Taike
    Zhang, Qian-Feng
    Leung, Wa-Hung
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 936 (1-3) : 15 - 18
  • [44] [ET4N][ME4SN2F5], AN UNUSUAL FLUOROSTANNATE(IV)
    LAMBERTSEN, TH
    JONES, PG
    SCHMUTZLER, R
    POLYHEDRON, 1992, 11 (03) : 331 - 334
  • [45] Synthesis,Structure and Reaction of a New Bitungsten Compound:（Et4N）2W2S4 （tdt）2
    YU Rong-Min
    LU Shao-Fang
    CHEN Hong-Bing
    HUANG Xiao-Ying
    WU Qiang-Jin
    HUANG Jian-Quan(State Key Laboratory of Structural Chemistry and Fujian Institute of Research onthe Structure of Matter
    结构化学, 1998, (01) : 18 - 23
  • [46] STRUCTURE OF [ET4N][INI(CO(CO)4)3]
    CLARKSON, LM
    FARRUGIA, LJ
    NORMAN, NC
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 2525 - 2526
  • [47] FORMATION AND CRYSTAL STRUCTURE OF （Et4N）2[Fe（SC6H4CH3-P）4]
    Kang Beisheng and Cai JinhuaFujian Institute of Research on the Structure of Matter
    结构化学, 1985, (02) : 119 - 122
  • [48] Thermal analysis of copper(h) complexes of general formula [Et4N]2[CuBrnCl4-n]
    Styczen, E.
    Jozwiak, W. K.
    Gazda, M.
    Wyrzykowski, D.
    Warnke, Z.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 91 (03) : 979 - 984
  • [49] POLYSULFONYLAMINES, PT-50, SYNTHESIS OF N,N-DIMESYLAMIDOSULFATES AND N,N-DIMESYLAMIDODISULFATES - SOLID-STATE STRUCTURE OF ET4N[O3SN(SO2ME)2] AND ET4N[O3SOSO2N(SO2ME)2]
    BLASCHETTE, A
    HIEMISCH, O
    SCHACHTER, H
    SAFARI, F
    JONES, PG
    LANGE, I
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 82 (1-4): : 141 - 162
  • [50] Synthesis and Crystal Structure of（Et4N）3[{V（o-C6H4OS）3}2Na]
    Wen Ting-Bin
    Xu Yong-Jin
    Shi Ji-Cheng
    Deng Yu-Heng
    Chen Chang-Neng
    Liu Qiu-Tian
    Kang Bei-Sheng
    (State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter
    结构化学, 1995, (02) : 151 - 156
12345