Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis[dichloridomercury(II)] N,N-dimethylformamide disolvate

被引:3
|
作者
Huang, Li-Hua [1 ]
Wu, Jie [1 ]
机构
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
关键词
CHEMISTRY;
D O I
10.1107/S1600536808040269
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the binuclear title complex, [Hg2Cl4(C17H13N5O2)(2)]center dot 2C(3)H(7)NO, contains one-half of the centro-symmetric molecule and one dimethylformamide solvent molecule. The Hg-II atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted tetrahedral coordination geometry. Intramolecular N-H center dot center dot center dot O hydrogen bonds may be effective in the stabilization of the structure. In the crystal structure, pi-pi contacts between pyridine rings [centroid-to-centroid distances 3.629 (3) and 3.595 (3) angstrom] may further stabilize the structure.
引用
收藏
页码:M15 / U272
页数:11
相关论文
共 50 条
  • [21] catena-Poly[[[bis(N,N-dimethylformamide)iron(II)]-{μ-2,2′-bis(diphenylphosphinoyl)-N,N′-[(1R,2R)-cyclohexane-1,2-diyl]dibenzamide}]bis(perchlorate) N,N-dimethylformamide disolvate]
    Ferrell, Grant R.
    Moore, Curtis
    Rheingold, Arnold L.
    Daley, Christopher J. A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1512 - U186
  • [22] {Bis(N,N-dimethylformamide)[μ-N,N′-bis(salicylidene)-1,3-propane-diaminato]nickel(II)}dibromozinc(II)
    Arici, C
    Svoboda, I
    Sari, M
    Atakol, O
    Fuess, H
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 : 31 - 32
  • [23] Tetrakis(μ-naphthalene-1-acetato-κ2O:O)bis[(N,N-dimethylformamide-κO)copper(II)] N, N-dimethylformamide disolvate
    Xia, H. -T
    Liu, Y. -F
    Li, S. -A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2653 - M2655
  • [24] Trichlorido(N,N-dimethylformamide-κO)bis(1,10-phenanthroline-κ2N,N′)-lanthanum(III) N,N-dimethylformamide disolvate
    Zhou, Li-Ming
    Sun, Guang-Hui
    Gao, Li-Jun
    Fang, Shao-Ming
    Yan, Wei-Dong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2637 - U127
  • [25] catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis(3-pyridylaminomethyl) benzene-κ2N:N'] N,N-dimethylformamide monosolvate]
    Gao, Shan
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1051 - U504
  • [26] N,N '-Diethyl-N,N '-diphenylpyridine-2,6-dicarboxamide
    Klepetarova, Blanka
    Makrlik, Emanuel
    Babain, Vasily A.
    Kasicka, Vaclav
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1099 - +
  • [27] Bis[benzyl N′-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-κ2N′,S]nickel(II) N,N-dimethylformamide disolvate
    Khaledi, Hamid
    Ali, Hapipah Mohd
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1615 - U1249
  • [28] N,N′-Bis[2-(2-pyridyl)methyl]pyridine-2,6-dicarboxamide hemihydrate
    Qi, JY
    Chen, J
    Yang, QY
    Zhou, ZY
    Chan, ASC
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : O1232 - O1233
  • [29] Synthesis of complexes with the polydentate ligand N,N′-bis(2-hydroxyphenyl)-pyridine-2,6-dicarboxamide
    Perez, Yolanda
    Johnson, Andrew L.
    Raithby, Paul R.
    POLYHEDRON, 2011, 30 (02) : 284 - 292
  • [30] N,N'-Bis(aryl)pyridine-2,6-dicarboxamide complexes of ruthenium: Synthesis, structure and redox properties
    Dasgupta, Moutusi
    Nag, Sumon
    Das, Gopal
    Nethaji, Munirathinam
    Bhattacharya, Samaresh
    POLYHEDRON, 2008, 27 (01) : 139 - 150