Thermal analyses and spectral characterization of some synthesized metal(II) Schiff base complexes

被引:13
|
作者
Jain, Rajendra K. [1 ]
Mishra, A. P. [1 ]
Gupta, Priya [1 ]
机构
[1] Dr HS Gour Cent Univ, Dept Chem, Synthet Inorgan & Coordinat Chem Labs, Sagar 470003, Madhya Pradesh, India
关键词
Schiff base complexes; Spectral analyses; Thermal analyses; COPPER(II) COMPLEXES; NICKEL(II); DECOMPOSITION; COBALT(II); BEHAVIOR; CU(II); CO(II); NI(II);
D O I
10.1007/s10973-012-2401-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
Schiff base metal complexes derived from 2-thiophenecarboxylidine-4-anisidine, 3,4-dihydroxy-5-nitrobenzylidine-2-amino-5-methylthiazole and 3,4-dihydroxy-5-nitrobenzylidine-4-chloroaniline have been synthesized and characterized by elemental analysis, IR, UV-Vis, molar conductance and thermal analyses. The complexes are coloured and stable in air at room temperature. The complexes exhibit coordination number to be 4 and 6. The thermal behaviour of metal complexes shows that the hydrated complexes lose water molecules of hydration in the first and then is immediately followed by decomposition of ligand molecules in the subsequent steps.
引用
收藏
页码:529 / 534
页数:6
相关论文
共 50 条
  • [41] Thermal, magnetic, ESR and antibacterial study of some Schiff base metal complexes
    Khare, M
    Mishra, AP
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2000, 77 (05) : 256 - 258
  • [42] Schiff base complexes of Iron(II) and their spectral properties
    Mehta, BH
    Purandare, KV
    ASIAN JOURNAL OF CHEMISTRY, 1998, 10 (01) : 175 - 179
  • [43] Synthesis and Spectral Analysis of Some New Metal Complexes of Mixed Schiff Base ligands
    Mahmoud, Waleed A.
    Abd Al-Iteef, Mariam S.
    RESEARCH JOURNAL OF PHARMACEUTICAL BIOLOGICAL AND CHEMICAL SCIENCES, 2018, 9 (04): : 108 - 118
  • [44] Microwave synthesis and spectral, thermal and antimicrobial activities of some novel transition metal complexes with tridentate Schiff base ligands
    Jain, Rajendra K.
    Mishra, Anand P.
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2012, 77 (08) : 1013 - 1029
  • [45] Antimicrobial agents: synthesis, spectral, thermal, and biological aspects of a polymeric Schiff base and its polymer metal(II) complexes
    Nishat, Nahid
    Khan, Shamim Ahmad
    Parveen, Shadma
    Rasool, Raza
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (22) : 3944 - 3955
  • [46] Preparation, spectroscopic characterisation and thermal analyses studies of the Cu(II), Pd(II) and VO(IV) complexes of some Schiff base ligands
    Tumer, M
    Erdogan, B
    Koksal, H
    Serin, S
    Nutku, MY
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1998, 28 (04): : 529 - 542
  • [47] SYNTHESIZED AND HYPOTHESIZED SCHIFF BASE LIGAND AND ITS METAL(II) COMPLEXES DNA BINDING MODE
    Puthilibai, G.
    Devatarika, V.
    Haewon, Byeon
    Behura, Shyam Sundar
    Lautre, Hitendra Kumar
    Subha, V.
    Sangwan, Pardeep
    Sunil, J.
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2023, 37 (05) : 1133 - 1139
  • [48] Synthesis, characterization, electrochemical and biological studies on some metal(II) Schiff base complexes containing quinoxaline moiety
    Dhanaraj, Chellaian Justin
    Johnson, Jijo
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 118 : 624 - 631
  • [49] Synthesis, spectral characterization and DNA cleavage study of heterocyclic Schiff base metal complexes
    Raman, N.
    Raja, S. Johnson
    Joseph, J.
    Raja, J. Dhaveethu
    JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2007, 52 (02): : 1138 - 1141
  • [50] Synthesis and Spectral Characterization of Some Transition Metal Complexes Containing Pentadentate SNNNS Donor Heterocyclic Schiff Base Ligands
    Kalagouda B. Gudasi
    Siddappa A. Patil
    Ramesh S. Vadavi
    Rashmi V. Shenoy
    Manjula S. Patil
    Transition Metal Chemistry, 2005, 30 : 1014 - 1019