Synthesis and characterization of rhenium(I) 4,4′-dicarboxy-2,2′-bipyridine tricarbonyl complexes for solar energy conversion

被引：11

作者：

Komreddy, Venugopal ^{[1
]}

Ensz, Kevin ^{[1
]}

Nguyen, Huy ^{[1
]}

Rillema, D. Paul ^{[1
]}

机构：

[1] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

来源：

INORGANICA CHIMICA ACTA | 2020年 / 511卷 / 511期

基金：

美国国家科学基金会;

关键词：

Rhenium(1); Carboxylic acid; Electronic spectra; Acid/base; DSSC; PHOTOPHYSICAL PROPERTIES; EXCITED-STATES; DYE; RUTHENIUM(II); REDUCTION; LIGANDS; TIO2; CO2; LUMINESCENCE; BIPYRIDYL;

D O I：

10.1016/j.ica.2020.119815

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a series of rhenium(I) tricarbonyl complexes containing 4,4 '-dicarboxy-2,2 '-bipyridine (dcbpy) and various halide or pseudohalide ligands is reported. Deprotonation of the carboxylates occurs in basic medium resulting in upfield H-1 NMR shifts for the protons of the carboxyl groups attached to 2,2 '-bipyridine. Metal-to-ligand charge transfer (MLCT) due to d pi -> pi* transitions systematically shift in the halide series from 382 nm for Re(dcbpy)(CO)(3)F to 436 nm for Re(dcbpy)(CO)(3)I. The compounds emit in the 600-650 nm region and have emission lifetimes greater than 50 ns. The solar energy conversion efficiency is less than 1% when TiO2- Re(dcbpy)(CO)(3)X, (X = F, CN, SCN, Br, I), photoanodes are used in Gratzel cells.

引用

页数：8

共 50 条

[41] (Acetonitrile)(2,2′-bipyridine)tricarbonyl-rhenium(I) perchlorate
Chen, YD
Zhang, LY
Chen, ZN
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M121 - M122
[42] Synthesis, characterization and antibacterial activity of ruthenium complex bearing 3,3'-dicarboxy-2,2'-bipyridine ligand
Al-Wahish, Mohammed A.
Saadh, Mohamed
Salama, Ali H.
PHARMACIA, 2023, 70 (02) : 405 - 410
[43] COPPER(I) COMPLEXES OF 4,4',6,6'-TETRAMETHYL-2,2'-BIPYRIDINE
LINNELL, RH
MANFREDI, D
JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (04): : 497 - 499
[44] Synthesis, characterization and crystal structure of 6-Chloro-4,4′-dimethyl-2,2′-bipyridine and 4,4′-Dimethyl 2,2′-bipyridine N-Oxide
Conterosito, Eleonora
Magistris, Claudio
Barolo, Claudia
Croce, Gianluca
Milanesio, Marco
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1107 : 337 - 343
[45] RESONANCE RAMAN-SPECTRA OF IRON(II) COMPLEXES WITH 4,4'-DIDODECYLOXY-2,2'-BIPYRIDINE AND "4,4'-DIOCTADECYLOXY-2,2'-BIPYRIDINE
KOWAL, AT
SKARZEWSKI, J
MONATSHEFTE FUR CHEMIE, 1984, 115 (8-9): : 953 - 959
[46] Direct observation of the solvent organization and nuclear vibrations of [Ru(dcbpy)2(NCS)2]4-, [dcbpy = (4,4′-dicarboxy-2,2′-bipyridine)], via ab initio molecular dynamics
Perrella, Fulvio
Petrone, Alessio
Rega, Nadia
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 23 (40) : 22885 - 22896
[47] A ONE-POT SYNTHESIS OF TETRAHYDRONIUM TRIS(4,4′-DICARBOXY LATO-2,2′-BIPYRIDINE)-RUTHENIUM(II) DIHYDRATE
Nazeeruddin, MK
Kalyanasundaram, K
Grätzel, M
Sullivan, BP
Morris, K
INORGANIC SYNTHESES, VOL 32, 1998, 32 : 181 - 186
[48] CONFORMATIONAL STUDIES ON RACEMIC 4,4'-DICARBOXY-2,2',5,5'-TETRAMETHYL-3,3'-BISELENIENYL
AURIVILLIUS, B
CHEMICA SCRIPTA, 1971, 1 (01): : 25 - +
[49] The ligand, the metal and the 'Holey'-host:: Synthesis, structural and magnetic characterisation of Co(II), Ni(II) and Mn(II) metal-organic frameworks incorporating 4,4′-dicarboxy-2,2′-bipyridine
Tynan, E
Jensen, P
Kelly, NR
Kruger, PE
Lees, AC
Moubaraki, B
Murray, KS
DALTON TRANSACTIONS, 2004, (21) : 3440 - 3447
[50] Improved synthesis of 4,4′-diamino-2,2′-bipyridine from 4,4′-dinitro-2,2′-bipyridine-N,N′-dioxide
Kavanagh, P
Leech, D
TETRAHEDRON LETTERS, 2004, 45 (01) : 121 - 123

← 1 2 3 4 5 →