Synthesis, Structures, and Antimicrobial Activity of Zinc and Copper Complexes Derived From N-isopropyl-N′-(1-pyridin-2-ylethylidene)ethane-1,2-diamine

被引：8
|
作者：
Hu, Xiao-Ming [1 ]
Xue, Ling-Wei [1 ]
Zhao, Gan-Qing [1 ]
Han, Yong-Jun [1 ]
机构：
[1] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467000, Henan, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 04期
关键词：
synthesis; crystal structure; antimicrobial; Schiff base; zinc complex; CRYSTAL-STRUCTURE; ANTIBACTERIAL; THIOCYANATE; NICKEL(II); ABSORPTION;
D O I：
10.1080/15533174.2011.613884
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Schiff base N-isopropyl-N'-(1-pyridin-2-ylethylidene)ethane-1,2-diamine (L) derived from 2-acetylpyridine and N-isopropylethane-1,2-diamine, and its mononuclear zinc(II) and polymeric copper(II) complexes, [ZnL(NCS)(2)] and [CuL(mu(2)-NCS)](n)center dot nBF(4), have been prepared and characterized by elemental analyses, IR, and single-crystal X-ray crystallographic determination. The Schiff base coordinates to the metal atoms through the three N atoms. The Zn atom in [ZnL(NCS)(2)] adopts a trigonal-bipyramidal coordination, and the Cu atom in [CuL(mu(2)-NCS)](n)center dot nBF(4) adopts a square-pyramidal coordination. The effect of the complexes on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied.
引用
收藏
页码：557 / 562
页数：6
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