Synthesis, Structures, and Antimicrobial Activity of Zinc and Copper Complexes Derived From N-isopropyl-N′-(1-pyridin-2-ylethylidene)ethane-1,2-diamine

被引：8

作者：

Hu, Xiao-Ming ^{[1
]}

Xue, Ling-Wei ^{[1
]}

Zhao, Gan-Qing ^{[1
]}

Han, Yong-Jun ^{[1
]}

机构：

[1] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467000, Henan, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 04期

关键词：

synthesis; crystal structure; antimicrobial; Schiff base; zinc complex; CRYSTAL-STRUCTURE; ANTIBACTERIAL; THIOCYANATE; NICKEL(II); ABSORPTION;

D O I：

10.1080/15533174.2011.613884

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Schiff base N-isopropyl-N'-(1-pyridin-2-ylethylidene)ethane-1,2-diamine (L) derived from 2-acetylpyridine and N-isopropylethane-1,2-diamine, and its mononuclear zinc(II) and polymeric copper(II) complexes, [ZnL(NCS)(2)] and [CuL(mu(2)-NCS)](n)center dot nBF(4), have been prepared and characterized by elemental analyses, IR, and single-crystal X-ray crystallographic determination. The Schiff base coordinates to the metal atoms through the three N atoms. The Zn atom in [ZnL(NCS)(2)] adopts a trigonal-bipyramidal coordination, and the Cu atom in [CuL(mu(2)-NCS)](n)center dot nBF(4) adopts a square-pyramidal coordination. The effect of the complexes on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied.

引用

页码：557 / 562

页数：6

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