Nickel(0)/imidazolium chloride catalyzed reduction of aryl halides

被引：133
|
作者：
Desmarets, C [1 ]
Kuhl, S [1 ]
Schneider, R [1 ]
Fort, Y [1 ]
机构：
[1] Univ Henri Poincare, UMR 7565, Fac Sci, F-54506 Vandoeuvre Les Nancy, France
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 08期
关键词：
D O I：
10.1021/om010949+
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dehalogenation of aryl halides was efficiently performed in refluxing THF using a catalytic combination composed of Ni(0)/N-heterocyclic carbene (NHC)/beta-hydrogen-containing alkoxide. 1Mes.HCl (1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride) and Ni(acac)2 used respectively as carbene and Ni(0) precursors associated to in situ generated i-PrONa were found to be the most effective for the dehalogenation of functionalized aryl chlorides, bromides, iodides, and polyhalogenated hydrocarbons.
引用
收藏
页码：1554 / 1559
页数：6
相关论文
共 50 条
  • [41] Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source
    Wen, Xue-Ping
    Han, Yu-Ling
    Chen, Jian-Xin
    RSC ADVANCES, 2017, 7 (71): : 45107 - 45112
  • [42] Nickel-catalyzed electrochemical reductive relay cross-coupling of alkyl halides to aryl halides
    Science Foundation in China, 2020, (02) : 31 - 31
  • [43] Nickel-Catalyzed Electrochemical Reductive Relay Cross-Coupling of Alkyl Halides to Aryl Halides
    Jiao, Ke-Jin
    Liu, Dong
    Ma, Hong-Xing
    Qiu, Hui
    Fang, Ping
    Mei, Tian-Sheng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (16) : 6520 - 6524
  • [44] Nickel-catalyzed direct difluoromethylation of aryl halides and triflates at room temperature
    Xu, Long
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [45] HALIDE EXCHANGE-REACTIONS BETWEEN ARYL HALIDES AND ALKALI-HALIDES CATALYZED BY NICKEL METAL
    YANG, SH
    LI, CS
    CHENG, CH
    JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (04): : 691 - 694
  • [46] Surprising role of aryl halides in nickel-catalyzed reductive aldol reactions
    Chrovian, Christa C.
    Montgomery, John
    ORGANIC LETTERS, 2007, 9 (03) : 537 - 540
  • [47] Electrochemical-Promoted Nickel-Catalyzed Reductive Allylation of Aryl Halides
    Chen, Wangzhe
    Ni, Shengyang
    Wang, Yi
    Pan, Yi
    ORGANIC LETTERS, 2022, 24 (20) : 3647 - 3651
  • [48] Nickel-catalyzed cyanation reaction of aryl/alkenyl halides with alkyl isocyanides
    Zhang, Yanling
    Zhang, Zhiguo
    Hu, Yuanyuan
    Liu, Yunkui
    Jin, Hongwei
    Zhou, Bingwei
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (41) : 8049 - 8053
  • [49] PHASE-TRANSFER CATALYSIS IN THE NICKEL-CATALYZED CYANATION OF ARYL HALIDES
    CASSAR, L
    FOA, M
    MONTANARI, F
    MARINELLI, GP
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 173 (03) : 335 - 339
  • [50] Mechanism of the nickel-catalyzed electrosynthesis of ketones by heterocoupling of aryl and benzyl halides
    Amatore, C
    Jutand, A
    Périchon, J
    Rollin, Y
    MONATSHEFTE FUR CHEMIE, 2000, 131 (12): : 1293 - 1304
12345