Synthesis, crystal and molecular structure of 1,3-bis[5-(3-methylisoxazolino-2)]-1,1,3,3-tetraphenyldisiloxane

被引:0
|
作者
Lukevics, E [1 ]
Dirnens, V [1 ]
Arsenyan, P [1 ]
Popelis, J [1 ]
Kemme, A [1 ]
机构
[1] LATVIAN INST ORGAN SYNTH,RIGA 1006,LATVIA
来源
MAIN GROUP METAL CHEMISTRY | 1996年 / 19卷 / 03期
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The addition of acetonitrile oxide to 1,3-divinyl-1,1,3,3-tetraphenyldisiloxane affords 1,3-bis[5-(3-methylisoxazolino-2)]-1,1,3,3-tetraphenyldisiloxane, the latter exists as a mixture of R,S- and R,R-diastereoisomers. The bond angle of Si-O-Si fragment in R,S-isomer equals 180(0)degrees and in R,R-isomer it is 172.8(2)degrees.
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页码:167 / 174
页数:8
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