Synthesis, Crystal Structure, and Fluorescent Property of a New Two-Dimensional Zn(II) Coordination Polymer Based on Oxalic Acid and 1,4-Bis(imidazol-1-ylmethyl)-butane

被引：2
|
作者：
Li, Xiu-Mei [1 ]
Qi, Xiao-Fei [2 ]
Ji, Jian-Ye [1 ]
Niu, Yan-Ling [1 ]
Wang, Qing-Wei [2 ]
机构：
[1] Tonghua Normal Univ, Fac Chem, Tonghua, Peoples R China
[2] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Minist Educ, Coll Chem, Siping 136000, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 05期
关键词：
coordination polymer; crystal structure; hydrothermal synthesis; METAL-ORGANIC FRAMEWORK; LUMINESCENT PROPERTIES; MAGNETIC-PROPERTIES; LIGANDS; CADMIUM(II); COMPLEXES; ZINC(II); BIS(IMIDAZOLE); SERIES; UNITS;
D O I：
10.1080/15533174.2013.790436
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound [Zn(C2O4)(bimb)](n)center dot nH(2)O (1) (H2C2O4 = oxalic acid, bimb = 1,4-bis(imidazol-1-yl)-butane) has been synthesized by hydrothermal reaction and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. Compound 1 exhibits two-dimensioanl layer structure. The intermolecular O-H center dot center dot center dot O interactions extend the compound 1 into 3D supramolecular architectures and play an important role in stabilizing compound 1. Furthermore, the solid-state fluorescence spectrum of the compound 1 was studied. The compound 1 exhibits intense broad emission at 520 nm at room temperature.
引用
收藏
页码：765 / 770
页数：6
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