Absorption characteristics of a quantum dot array induced intermediate band: Implications for solar cell design

被引:116
|
作者
Tomic, Stanko [1 ]
Jones, Tim S. [2 ]
Harrison, Nicholas M. [1 ,3 ]
机构
[1] STFC Daresbury Lab, Dept Computat Sci & Engn, Warrington WA4 4AD, Cheshire, England
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
关键词
electronic structure; energy gap; Fermi level; gallium arsenide; III-V semiconductors; indium compounds; infrared spectra; Raman spectra; semiconductor quantum dots; solar cells; visible spectra;
D O I
10.1063/1.3058716
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present a theoretical study of the electronic and absorption properties of the intermediate band (IB) formed by a three dimensional structure of InAs/GaAs quantum dots (QDs) arranged in a periodic array. Analysis of the electronic and absorption structures suggests that the most promising design for an IB solar cell material, which will exhibit its own quasi-Fermi level, is to employ small QDs (6-12 nm QD lateral size). The use of larger QDs leads to extension of the absorption spectra into a longer wavelength region but does not provide a separate IB in the forbidden energy gap.
引用
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页数:3
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