On nascent angular-momentum distributions in complex-forming bimolecular reactions

被引：16
|
作者：
Olzmann, M
机构：
[1] Institut für Physikalische Chemie, Universität Halle-Wittenberg, FB Chemie Merseburg
来源：
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1997年 / 101卷 / 03期
关键词：
chemical kinetics; elementary reactions; reaction dynamics;
D O I：
10.1002/bbpc.19971010328
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A detailed modelling of a complex-forming bimolecular reaction requires the knowledge of the nascent energy and angular-momentum distribution of the intermediate complex. A method is presented to calculate the distribution of the orbital angular momenta as a result of reactive collisions in a radial potential. For the case of thermal collisions, analytical solutions are obtained. Reactions of photochemically generated species are also considered. The method is applied to the reaction of CH4 with O-2(+) and O(D-1), respectively.
引用
收藏
页码：533 / 537
页数：5
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