Transition metal-free oxidation of activated alcohols to aldehydes and ketones in 1,1,1,3,3,3-hexafluoro-2-propanol

被引：13
|
作者：
Khaksar, Samad [1 ]
Talesh, Saeed Mohammadzadeh [1 ]
机构：
[1] Islamic Azad Univ, Dept Chem, Ayatollah Amoli Branch, Amol, Iran
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2012年 / 140卷
关键词：
Fluorinated alcohols; Oxidation; Sodium hypochlorite; Aldehyde; TRANSFER CATALYTIC-SYSTEMS; SELECTIVE OXIDATION; FLUORINATED ALCOHOLS; AEROBIC OXIDATION; SODIUM-HYPOCHLORITE; SECONDARY ALCOHOLS; AU CLUSTERS; EFFICIENT; SOLVENTS; OXIDANT;
D O I：
10.1016/j.jfluchem.2012.05.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple and convenient procedure for the oxidation of various benzylic, allylic and some aliphatic alcohols to their corresponding carbonyl compounds is described using sodium hypochlorite as the oxidant in 1,1,1,3,3,3-hexafluoro-2-propanol without use of a catalyst or any other additive. The solvent can be readily recovered from reaction products in excellent purity for direct reuse. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：95 / 98
页数：4
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