Metal complexes of tripodal ligands as ionophores for alkali metal ions

被引：7

作者：

Katsuta, Shoichi ^{[1
]}

Shimizu, Yuichi ^{[1
]}

Takahashi, Ryota ^{[1
]}

Kanaya, Naoki ^{[1
]}

Imoto, Takahiro ^{[1
]}

Takeda, Yasuyuki ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 07期

基金：

日本学术振兴会;

关键词：

EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; EXTRACTION; PICRATES; TB; GD; NA; LN;

D O I：

10.1039/c2nj40171a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrically neutral metal(III) complexes of tripodal ligands, 1,1,1-tris[(salicylideneamino)methyl]ethane and 1,1,1-tris[(3-methoxysalicylideneamino)methyl]ethane, were found to function as ionophores for alkali metal ions. The complexes of the latter ligand extract alkali metal picrates from aqueous solutions into dichloromethane with a similar selectivity to that of dibenzo-24-crown-8.

引用

页码：1445 / 1448

页数：4

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