A new ladder-type silver(I) coordination polymer with 4,4′-bipyridine and 4-[(4-carboxybenzyloxy)methyl]benzoate ligands: synthesis, crystal structure, fluorescence properties and Hirshfeld surface analysis

被引：2
|
作者：
Chen, Zhao [1 ]
Zhang, Zilong [1 ]
Zhang, Chong [1 ]
Xiao, Yu [1 ,2 ]
机构：
[1] Guilin Univ Technol, Guangxi Collaborat Innovat Ctr Water Pollut Contr, Guangxi Min & Environm Sci Lab Ctr, Guilin 541004, Peoples R China
[2] Guangdong Univ Petrochem Technol, Sch Environm Sci & Engn, Maoming 525000, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2020年 / 76卷
基金：
美国国家科学基金会;
关键词：
silver; bipyridine; dibenzoic acid; crystal structure; fluorescence; ladder-type coordination polymer; ACID; PHOTOLUMINESCENT; CHEMISTRY;
D O I：
10.1107/S2053229620011882
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel ladder-type coordination polymer (CP), poly[(mu-4,4'-bipyridine-kappa N-2:N'){mu-4-[(4-carboxybenzyloxy)methyl]benzoato-kappa O}silver(I)](Ag-Ag), [Ag(C16H13O5)(C10H8N2)]n or [Ag(HL)(4,4'-bpy)](n) {H2L is 4,4'-[oxybis(methylene)]dibenzoic acid and 4,4'-bpy is 4,4'-bipyridine}, was synthesized using hydrothermal methods. The complex was characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction, and is a ladder-type CP which exhibits an obvious Ag-Ag interaction. The legs of the ladder are formed by parallel 4,4'-bipy ligands and silver ions, and the rungs are constructed by Ag-Ag interactions. A Hirshfeld surface analysis was carried out and is discussed in detail. The complex also displays favourable fluorescence properties.
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收藏
页码：952 / +
页数：13
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