Synthesis of Heterogeneous Copper Catalyst Based on Amino-Functionalized Triazine Rings Supported by Silica-Gel for Oxidation of Alcohols

被引:5
|
作者
Kolahdoozan, Majid [1 ,2 ]
Kalbasi, Roozbeh Javad [1 ]
Hossaini, Mahshid [1 ]
机构
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Esfahan 86145, Iran
[2] Islamic Azad Univ, Shahreza Branch, Young Researcher Club, Esfahan 86145, Iran
关键词
SELECTIVE OXIDATION; COVALENT ATTACHMENT; CYANURIC CHLORIDE; EPOXY-RESIN; EFFICIENT; COMPLEXES; EPOXIDATION; ALDEHYDES; SOLVENT; KETONES;
D O I
10.1155/2013/749723
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amino-functionalized triazine supported on silica-gel was prepared. This new triazine derivate was applied as a coordinating agent for copper (II) and was characterized by different methods. The copper (II) content of the material was determined by atomic absorption. This novel transition metal supported on heterogeneous surface was used as an effective catalyst for oxidation of benzylic alcohols in the presence of H2O2. This catalyst can be reused without any significant loss of activity.
引用
收藏
页数:7
相关论文
共 50 条
  • [31] Platinum nanoparticles supported on polymeric ionic liquid functionalized magnetic silica: effective and reusable heterogeneous catalysts for the selective oxidation of alcohols in water
    Vessally, Esmail
    Ghasemisarabbadeih, Mostafa
    Ekhteyari, Zeynab
    Hosseinzadeh-Khanmiri, Rahim
    Ghorbani-Kalhor, Ebrahim
    Ejlali, Ladan
    RSC ADVANCES, 2016, 6 (108): : 106769 - 106777
  • [32] Adsorption kinetics and equilibrium of copper from ethanol fuel on silica-gel functionalized with amino-terminated dendrimer-like polyamidoamine polymers
    Qu, Rongjun
    Sun, Changmei
    Ma, Fang
    Cui, Zhenzhong
    Zhang, Ying
    Sun, Xiaoying
    Ji, Chunnuan
    Wang, Chunhua
    Yin, Ping
    FUEL, 2012, 92 (01) : 204 - 210
  • [33] A silica gel supported cobalt(Ⅱ) Schiff base complex as efficient and recyclable heterogeneous catalyst for the selective aerobic oxidation of alkyl aromatics
    Lei Chen
    Bin-Dong Li
    Qiu-Xia Xu
    Da-Bin Liu
    ChineseChemicalLetters, 2013, 24 (09) : 849 - 852
  • [34] A crowned manganese-based Schiff complex supported on nanocellulose as an efficient and sustainable heterogeneous catalyst for the oxidation of benzyl alcohols
    Maleki, Behrooz
    Sandaroos, Reza
    Naderi, Sanaz
    Peiman, Sahar
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2023, 990
  • [35] A silica gel supported cobalt(II) Schiff base complex as efficient and recyclable heterogeneous catalyst for the selective aerobic oxidation of alkyl aromatics
    Chen, Lei
    Li, Bin-Dong
    Xu, Qiu-Xia
    Liu, Da-Bin
    CHINESE CHEMICAL LETTERS, 2013, 24 (09) : 849 - 852
  • [37] Copper-supported thiol-functionalized cellulose as a paper-based catalyst for imine synthesis
    Sangkaworn, Jariyaporn
    Limprasart, Waranya
    Hoefler, Mark Valentin
    Gutmann, Torsten
    Pornsuwan, Soraya
    Bunchuay, Thanthapatra
    Tantirungrotechai, Jonggol
    SCIENTIFIC REPORTS, 2025, 15 (01):
  • [38] Nano-sized silica supported FeCl3 as an efficient heterogeneous catalyst for the synthesis of 1,2,4-triazine derivatives
    Habibi, Davood
    Vakili, Somayyeh
    CHINESE JOURNAL OF CATALYSIS, 2015, 36 (04) : 620 - 625
  • [39] Novel one-pot synthesis of 4H-chromene derivatives using amino functionalized silica gel catalyst
    Joshi, Vijaykumar M.
    Magar, Rupali L.
    Throat, Prashant B.
    Tekale, Sunil U.
    Patil, Bhagavan R.
    Kale, Mangal P.
    Pawar, Rajendra P.
    CHINESE CHEMICAL LETTERS, 2014, 25 (03) : 455 - 458
  • [40] Novel one-pot synthesis of 4H-chromene derivatives using amino functionalized silica gel catalyst
    Vijaykumar M.Joshi
    Rupali L.Magar
    Prashant B.Throat
    Sunil U.Tekale
    Bhagavan R.Patil
    Mangal P.Kale
    Rajendra P.Pawar
    Chinese Chemical Letters, 2014, 25 (03) : 455 - 458