Bis(phenylenedithio)tetrathiafulvalene (BPhDT-TTF): Synthesis and properties of a new pi-donor for organic metals

被引：2
|
作者：
Muller, H
Fiedler, S
Saad, M
Riekel, C
机构：
来源：
SYNTHETIC METALS | 1997年 / 86卷 / 1-3期
关键词：
heterocycle synthesis; electrocrystallisation; organic conductor;
D O I：
10.1016/S0379-6779(97)80952-6
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The new pi-donor bis(phenylenedithio)tetrathiafulvalene (7), synthesized via phosphite coupling of 2-oxo-1,3-dithiolo[4,5 b][1,4]benzodithiin (6) has been prepared in five steps starting from dimercaptobenzene (1) and chloroactyl chloride (2). Spectroscopic and electrochemical data of 7 are presented. Electrocrystallization yielded highly conducting radical cation salts (sigma(RT)=100 S/cm) as fibers (typical dimensions: 10000x50x20 mu m). Structural aspects, obtained on these salts by microdiffraction techniques, will be discussed.
引用
收藏
页码：1885 / 1886
页数：2
相关论文
共 50 条
  • [21] ORGANIC CONDUCTORS BASED ON MULTI-SULFUR PI-DONOR AND OR PI-ACCEPTOR MOLECULES - BEDT-TTF, BMDT-TTF, BPDT-TTF, AND M(DMIT)2
    KOBAYASHI, H
    KATO, R
    MORI, T
    KOBAYASHI, A
    SASAKI, Y
    SAITO, G
    INOKUCHI, H
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 125 (1-4): : 125 - 134
  • [22] Synthesis of a new extended pi-donor with 1,4-oxathiane annulation
    Hellberg, J
    Balodis, K
    Moge, M
    Korall, P
    vonSchutz, JU
    JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (01) : 31 - 34
  • [23] New organic metals based on bis-fused TTF donors
    Mori, T
    Kawamoto, T
    Misaki, Y
    Kawakami, K
    Fujiwara, H
    Yamabe, T
    Mori, H
    Tanaka, S
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 284 : 271 - 282
  • [24] IMPROVED SYNTHESIS OF ASYMMETRIC PI-DONOR MOLECULES EDT-TTF (ETHYLENEDITHIOTETRATHIAFULVALENE) AND EDTDM-TTF (ETHYLENEDITHIODIMETHYLTETRATHIAFULVALENE) - STRUCTURAL DETERMINATION AND ELECTROCHEMICAL STUDIES OF EDT-TTF
    GARREAU, B
    DEMONTAUZON, D
    CASSOUX, P
    LEGROS, JP
    FABRE, JM
    SAOUD, K
    CHAKROUNE, S
    NEW JOURNAL OF CHEMISTRY, 1995, 19 (02) : 161 - 171
  • [25] Synthesis and properties of bis(ethyleneseleno)tetrathiafulvalene (BES-TTF) and diselenolotetrathiafulvalene (DS-TTF) as novel electron donors
    Jigami, T
    Takimiya, K
    Aso, Y
    Otsubo, T
    CHEMISTRY LETTERS, 1997, (11) : 1091 - 1092
  • [26] ORGANIC METALS - SYNTHESIS AND SOLID-STATE PROPERTIES OF NEW EXTENDED TETRATHIAFULVALENE AND SELENATRITHIAFULVALENE DERIVATIVES
    BRYCE, MR
    MOORE, AJ
    PURE AND APPLIED CHEMISTRY, 1990, 62 (03) : 473 - 476
  • [27] SYNTHESIS OF A NEW WEITZ-TYPE ORGANOSULFUR PI-DONOR - 1,2-BIS(THIOXANTHEN-9-YLIDENE)ETHENE
    NAKASUJI, K
    TAKATOH, K
    NAKATSUKA, M
    MURATA, I
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (14) : 717 - 718
  • [28] A new molecular C60 complex with bis(methylenedithio)tetrathiafulvalene (BMDT-TTF): Synthesis, crystal structure, and properties
    N. G. Spitsina
    V. V. Gritsenko
    O. A. D’yachenko
    É. B. Yagubskii
    Physics of the Solid State, 2002, 44 : 531 - 533
  • [29] Synthesis of some functionalised isomeric bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and dithiophenetetrathiafulvalene (DTTTF) pi-donors
    Kumar, EVKS
    Singh, JD
    Singh, HB
    Das, K
    Verghese, B
    TETRAHEDRON, 1997, 53 (34) : 11627 - 11644
  • [30] A new molecular C60 complex with bis(methylenedithio)tetrathiafulvalene (BMDT-TTF):: Synthesis, crystal structure, and properties
    Spitsina, NG
    Gritsenko, VV
    D'yachenko, OA
    Yagubskii, ÉB
    PHYSICS OF THE SOLID STATE, 2002, 44 (03) : 531 - 533
12345