Reactions of Alkyl Peroxyl Radicals with Metal Nanoparticles in Aqueous Solutions

被引：12
|
作者：
Bar-Ziv, Ronen [1 ,2 ]
Zilbermann, Israel [1 ,2 ]
Zidki, Tomer [1 ]
Cohen, Haim [1 ,3 ]
Meyerstein, Dan [1 ,3 ]
机构：
[1] Ben Gurion Univ Negev, Dept Chem, Beer Sheva, Israel
[2] Nucl Res Ctr, Beer Sheva, Israel
[3] Ariel Univ Ctr Samaria, Dept Biol Chem, Ariel, Israel
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 08期
关键词：
ORGANIC FREE-RADICALS; COLLOIDAL SILVER; PULSE-RADIOLYSIS; PHYSICOCHEMICAL PROPERTIES; SEMICONDUCTOR PARTICLES; METHYLPEROXYL RADICALS; RATE CONSTANTS; GOLD; TRANSITION; RESONANCE;
D O I：
10.1021/jp809631v
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Methyl-peroxyl radicals react with Au-0 and Ag-0 nanoparticles (NPs) in aqueous suspensions in fast reaction with rate constants which approach the diffusion-controlled limit. The transients thus formed decompose via heterolysis of the O-O bond resulting in the oxidation of the NPs and formation of methanol.
引用
收藏
页码：3281 / 3286
页数：6
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