Reactions of Alkyl Peroxyl Radicals with Metal Nanoparticles in Aqueous Solutions

被引：12

作者：

Bar-Ziv, Ronen ^{[1
,2
]}

Zilbermann, Israel ^{[1
,2
]}

Zidki, Tomer ^{[1
]}

Cohen, Haim ^{[1
,3
]}

Meyerstein, Dan ^{[1
,3
]}

机构：

[1] Ben Gurion Univ Negev, Dept Chem, Beer Sheva, Israel

[2] Nucl Res Ctr, Beer Sheva, Israel

[3] Ariel Univ Ctr Samaria, Dept Biol Chem, Ariel, Israel

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 08期

关键词：

ORGANIC FREE-RADICALS; COLLOIDAL SILVER; PULSE-RADIOLYSIS; PHYSICOCHEMICAL PROPERTIES; SEMICONDUCTOR PARTICLES; METHYLPEROXYL RADICALS; RATE CONSTANTS; GOLD; TRANSITION; RESONANCE;

D O I：

10.1021/jp809631v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Methyl-peroxyl radicals react with Au-0 and Ag-0 nanoparticles (NPs) in aqueous suspensions in fast reaction with rate constants which approach the diffusion-controlled limit. The transients thus formed decompose via heterolysis of the O-O bond resulting in the oxidation of the NPs and formation of methanol.

引用

页码：3281 / 3286

页数：6

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