Synthesis and characterization of nickel(II), cobalt(III) and iron(III) complexes of the Schiff base 1-(2,3-dihydroxybenzylidene)thiosemicarbazone

被引：0

作者：

Al-Kubaisi, AH ^{[1
]}

Nour, EM ^{[1
]}

Eltayeb, MAZ ^{[1
]}

机构：

[1] Univ Qatar, Coll Sci, Dept Chem, Doha, Qatar

来源：

POLISH JOURNAL OF CHEMISTRY | 2004年 / 78卷 / 04期

关键词：

1-(2,3-dihydroxybenzylidene)thiosemicarbazone; cobalt(III); iron(III); nickel(II); complexes; infrared; thermal;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ni(II), Co(III) and Fe(III) complexes of the Schiff base 1-(2,3-dihydroxybenzylidene)thiosemicarbazone (Hdhbtsc) have been prepared and characterized by elemental analysis, infrared spectra, thermal analysis, molar conductivity and magnetic measurements. The results indicate the formation of 1:2 metal to ligand complexes with empirical formulae [Ni(Hdhbtsc)(2)(Cl)(2)] and [M(dhbtsc)(2)(Cl)(H2O)], (Hdhbtsc = the Schiff base; dhbtsc = anionic form of the Schiff base; M = Fe3+ or Co3+). The three new complexes are six coordinate and octahedral, where the ligands behave as bidentate chelating agents in the neutral form with Ni2+ and in the uninegatively charged form with Fe3+ or Co

引用

页码：515 / 520

页数：6

共 50 条

[21] Two new quadridentate Schiff base complexes of nickel(II) and cobalt(III): Synthesis, structure and spectral characterisation
Chakraborty, Joy
Singh, Raj K. Bhubon
Samanta, Brajagopal
Choudhury, Chirantan Roy
Dey, Subrata K.
Talukder, Pritha
Borah, Manob J.
Mitra, Samiran
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2006, 61 (10): : 1209 - 1216
[22] SYNTHESIS AND CHARACTERIZATION OF COPPER(II), COBALT(II-AND-III) AND NICKEL(II) COMPLEXES WITH FERROCENYL SCHIFF-BASES
DEY, K
NANDI, KK
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (10): : 908 - 913
[23] Synthesis, antimicrobial, DNA-binding and photonuclease studies of Cobalt(III) and Nickel(II) Schiff base complexes
Gowda, K. R. Sangeetha
Naik, H. S. Bhojya
Kumar, B. Vinay
Sudhamani, C. N.
Sudeep, H. V.
Naik, T. R. Ravikumar
Krishnamurthy, G.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 105 : 229 - 237
[24] Manganese (II), ferric (III), cobalt (II) and copper (II) thiosemicarbazone Schiff base complexes: Synthesis, spectroscopic, molecular docking and biological discussions
Al-Wasidil, Asma S.
Naglah, Ahmed M.
Al-Omar, Mohamed A.
Al-Obaid, Abdul-Rahman M.
Alosaimi, Eid H.
El-Metwaly, Nashwa M.
Refat, Moamen S.
Ahmed, Ahmed S.
El-Deen, Ibrahim M.
Soliman, Aida H.
Emam, Aml
MATERIALS EXPRESS, 2020, 10 (02) : 290 - 300
[25] Synthesis, characterization, structure, redox property, antibacterial and catalytic activity of tridentate Schiff base cobalt(III), nickel(II) and palladium(II) complexes
Pattanayak, Poulami
Pratihar, Jahar Lal
Patra, Debprasad
Lin, Chia-Her
Paul, Sobhana
Chakraborty, Kausiki
POLYHEDRON, 2013, 51 : 275 - 282
[26] SALICYLAMIDE COMPLEXES OF IRON(III), COBALT(II), AND NICKEL(II)
PANNU, BS
CHOPRA, SL
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 398 (01): : 83 - 87
[27] Antioxidant and antimicrobial properties of nickel(II), cobalt(III), and zinc(II) complexes of a Schiff base ligand
Qi-Meige Hasi
Yan Fan
Xiao-Xia Feng
Xiao-Qiang Yao
Jia-Cheng Liu
Transition Metal Chemistry, 2016, 41 : 685 - 692
[28] Antioxidant and antimicrobial properties of nickel(II), cobalt(III), and zinc(II) complexes of a Schiff base ligand
Hasi, Qi-Meige
Fan, Yan
Feng, Xiao-Xia
Yao, Xiao-Qiang
Liu, Jia-Cheng
TRANSITION METAL CHEMISTRY, 2016, 41 (06) : 685 - 692
[29] Iron(III), cobalt(II), nickel(II), copper(II) and zinc(II) complexes of 4-formylantipyrine thiosemicarbazone
ElSawaf, AK
West, DX
ElSaied, FA
ElBahnasawy, RM
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1997, 27 (08): : 1127 - 1147
[30] Iron(III), Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes of 4-Formylantipyrine Thiosemicarbazone
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27 (08):

← 1 2 3 4 5 →