Vibrational analysis of metal halide complexes of 1,2,4-triazole. Part One

被引：0

作者：

Zaydoun, S ^{[1
]}

Idrissi, MS

Lorriaux-Rubbens, A

Garrigou-Lagrange, C

机构：

[1] Fac Sci, Dept Chim, Lab Spect Infrarouge, Rabat, Morocco

[2] Univ Sci & Tech Lille Flandres Artois, Lab Spectrochim Infrarouge & Raman, F-59655 Villeneuve Dascq, France

[3] Ctr Rech Paul Pascal, F-33600 Pessac, France

来源：

CANADIAN JOURNAL OF ANALYTICAL SCIENCES AND SPECTROSCOPY | 1999年 / 44卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

1,2,4-triazole forms with transition, metal(ll) halides complexes of the general formula MX,TA and MX,TA,. A thorough vibrational analysis of these complexes and their deuterated analogs has been performed and fundamental vibrations of the ligand has been assigned. The coordination mode of triazole is proposed. The fact that the Ligand vibrations shift only slightly upon, coordination is accounted for by the existence of pi-back bonding from the metal ion to the ligand.

引用

页码：10 / 17

页数：8

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