Ionic iridium complex coordinated with tetrathiafulvalene-fused phenanthroline ligand: Synthesis, photophysical, electrochemical and electrochemiluminescence properties

被引：12

作者：

Qin, Jie ^{[1
,3
]}

Deng, Sheng-Yuan ^{[2
,4
]}

Qian, Chen-Xi ^{[3
]}

Li, Tian-Yi ^{[3
]}

Ju, Huang-Xian ^{[4
]}

Zuo, Jing-Lin ^{[3
]}

机构：

[1] Shandong Univ Technol, Sch Life Sci, Zibo 255049, Peoples R China

[2] Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Jiangsu, Peoples R China

[3] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[4] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Jiangsu, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 750卷

基金：

中国国家自然科学基金;

关键词：

Cationic iridium complex; Tetrathiafulvalene ligand; Photoluminescence; Electrochemiluminescence; ELECTRON-TRANSFER; REDOX; DONOR; 1ST; TTF; PHOSPHORESCENT; CHEMISTRY; STATES; GREEN;

D O I：

10.1016/j.jorganchem.2013.10.041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new cationic iridium(III) complex salt, [Ir(ppy)(2)(L)]PF6 (ppy = 2-phenylpyridine) (1), was synthesized by using tetrathiafulvalene fused 4',5'-dimethyldithiotetrathiafulvenyl[4,5-f][1,10]phenanthroline (L) as (NN)-N-boolean AND ancillary ligand. The photophysical, electrochemical and electrochemiluminescence (ECL) behavior of the complex are investigated. Complex 1 is found to be emissive at room temperature with the lambda(max) value at 607 nm. It is expected that this new luminescent complex 1 would be further explored for promising applications in functional emitting material. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：7 / 12

页数：6

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