Similarity approach to chemical reactivity. Theoretical justification of the Hammond postulate

被引：5

作者：

Ponec, R ^{[1
]}

Yuzhakov, G ^{[1
]}

Pecka, J ^{[1
]}

机构：

[1] CHARLES UNIV, DEPT ORGAN CHEM, PRAGUE 2, CZECH REPUBLIC

来源：

JOURNAL OF MATHEMATICAL CHEMISTRY | 1996年 / 19卷 / 3-4期

关键词：

D O I：

10.1007/BF01166718

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The recently proposed similarity index was applied to the quantitative justification of the empirical Hammond postulate for a series of selected pericyclic reactions. In keeping with the expectations of the postulate the transition states were shown to be reactant-like for exothermic and product-like for endothermic reactions.

引用

页码：265 / 270

页数：6

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