Triterpenoid saponins from the fruits of Aesculus pavia

被引：43
|
作者：
Zhang, Zhizhen
Li, Shiyou
Zhang, Shanmin
Gorenstein, David
机构：
[1] Stephen F Austin State Univ, Arthur Temple Coll Forestry & Agr, Natl Ctr Pharmaceut Crops, Ctr Municipal Plant Res, Nacogdoches, TX 75962 USA
[2] Univ Texas, Sealy Ctr Struct Biol, Dept Physiol & Biophys, Med Branch, Galveston, TX 77555 USA
来源：
PHYTOCHEMISTRY | 2006年 / 67卷 / 08期
关键词：
Aesculus pavia; hippocastanaceae; saponins; aesculiosides;
D O I：
10.1016/j.phytochem.2006.01.017
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The compounds, named aesculiosides Ia-Ie, IIa-IId, and IVa-IVc, were isolated from an ethanol extract of the fruits of North American Aesculus pavia, along with two known compounds. Their structures were characterized as polyhydroxyoleanene pentacyclic triterpenoid saponins by spectroscopic and chemical analyses. These saponins were divided into three elution zones by chromatography according to the polarity because of the acyl substitution at C-21 and C-22 of the aglycone saponins moiety. These are structurally different from those isolated from Eurasian Aesculus hippocastanum and Aesculus chinensis in their oligosaccharide moieties. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：784 / 794
页数：11
相关论文
共 50 条
  • [31] Caspicaosides E-K, triterpenoid saponins and cytotoxic acylated saponins from fruits of Gleditsia caspica Desf.
    Melek, F. R.
    Kassem, I. A. A.
    Miyase, Toshio
    Fayad, Walid
    PHYTOCHEMISTRY, 2014, 100 : 110 - 119
  • [32] Assamicin I and II, novel triterpenoid saponins with insulin-like activity from Aesculus assamica Griff.
    Sakurai, T
    Nishimura, T
    Otake, N
    Yao, XS
    Abe, K
    Zeida, M
    Nagasawa, H
    Sakuda, S
    BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2002, 12 (05) : 807 - 810
  • [33] New saponins from the seeds of Aesculus chinensis
    Zhang, ZZ
    Koike, K
    Jia, ZH
    Nikaido, T
    Guo, D
    Zheng, J
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1999, 47 (11) : 1515 - 1520
  • [34] Cytotoxic triterpenoid saponins acylated with monoterpenic acids from fruits of Gleditsia caspica Desf.
    Miyase, Toshio
    Melek, F. R.
    Warashina, Tsutomu
    Selim, M. A.
    El Fiki, N. M.
    Kassem, I. A. A.
    PHYTOCHEMISTRY, 2010, 71 (16) : 1908 - 1916
  • [35] STRUCTURE OF THE SAPOGENINS OF SEEDS FROM AESCULUS-PAVIA L
    SCHRUTKARECHTENSTAMM, R
    ROBIEN, W
    JURENITSCH, J
    PHARMAZIE, 1988, 43 (03): : 208 - 210
  • [36] Triterpenoid saponins from Campsiandra guayanensis
    Braca, A
    Abdel-Razik, AF
    Mendez, J
    De Tommasi, N
    JOURNAL OF NATURAL PRODUCTS, 2006, 69 (02): : 240 - 246
  • [37] Triterpenoid saponins from Herniaria fontanesii
    MBark, AN
    Guillaume, D
    Kol, O
    Charrouf, Z
    PHYTOCHEMISTRY, 1996, 43 (05) : 1075 - 1077
  • [38] TRITERPENOID SAPONINS FROM ZYGOPHYLLUM SPECIES
    ELGAMAL, MHA
    SHAKER, KH
    POLLMANN, K
    SEIFERT, K
    PHYTOCHEMISTRY, 1995, 40 (04) : 1233 - 1236
  • [39] Triterpenoid saponins from Hedyotis nudicaulis
    Konishi, M
    Hano, Y
    Takayama, M
    Nomura, T
    Hamzah, AS
    Ahmad, RB
    Jasmani, H
    PHYTOCHEMISTRY, 1998, 48 (03) : 525 - 528
  • [40] Triterpenoid saponins from Berneuxia thibetica
    Wang, MK
    Cai, H
    Peng, SL
    Ding, LS
    Wu, FE
    Chen, YZ
    PHYTOCHEMISTRY, 1998, 48 (08) : 1411 - 1414
12345