Tailoring Surface-Confined Nanopores with Photoresponsive Groups

被引：55
|
作者：
Tahara, Kazukuni [1 ]
Inukai, Koji [1 ]
Adisoejoso, Jinne [2 ]
Yamaga, Hiroyuki [1 ]
Balandina, Tatyana [2 ]
Blunt, Matthew O. [2 ]
De Feyter, Steven [2 ]
Tobe, Yoshito [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Div Frontier Mat Sci, Toyonaka, Osaka 5608531, Japan
[2] Katholieke Univ Leuven, Lab Photochem & Spect, Div Mol Imaging & Photon, Dept Chem, B-3001 Louvain, Belgium
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 32期
关键词：
annulenes; photochemistry; porous materials; scanning tunneling microscopy; self-assembly; MOLECULAR RECOGNITION; DERIVATIVES; NETWORKS; ISOMERIZATION; COORDINATION; AZOBENZENE;
D O I：
10.1002/anie.201303745
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Opening light: Two-dimensional pores are formed by the self-assembly of azobenzene-functionalized triangular building blocks on graphite at the liquid-solid interface. These pores can selectively host a guest molecule. The pore size can be reversibly changed by irradiation at different wavelength which changes the number of guest molecules that are adsorbed (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8373 / 8376
页数：4
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