Effect of imidazolium room-temperature ionic liquids on aggregation of amphotericin B: a circular dichroism study

被引：4
|
作者：
Jameson, Laramie P. [1 ]
Dzyuba, Sergei V. [1 ]
机构：
[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA
来源：
RSC ADVANCES | 2015年 / 5卷 / 98期
基金：
美国国家科学基金会;
关键词：
SELF-ASSOCIATION; ELECTRONIC ABSORPTION; POLYENE ANTIBIOTICS; SOLVATION; POLARITY; DRUGS; SALTS; ERGOSTEROL; DYNAMICS; BEHAVIOR;
D O I：
10.1039/c5ra17077j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The nature of the anion of imidazolium-based ionic liquids was found to control the aggregate-monomer equilibrium of amphotericin B. This is in contrast to aqueous solutions of inorganic salts and imidazolium-based ionic liquids, which were previously found to favor the disaggregation of amphotericin B. The results further establish the designer solvent ability of ionic liquids, specifically as it relates to their ability to influence intermolecular interactions.
引用
收藏
页码：80325 / 80329
页数：5
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