Electrochemical synthesis and characterization of conducting polymers using room temperature melt as an electrolyte

被引：7
|
作者：
Geetha, S [1 ]
Trivedi, DC [1 ]
机构：
[1] Cent Electrochem Res Inst, Ctr Conducting Polymers, Karaikkudi 630006, Tamil Nadu, India
来源：
SYNTHETIC METALS | 2005年 / 155卷 / 02期
关键词：
chloroaluminate; room temperature melt; conductivity; polypyrrole; polyparaphenylene;
D O I：
10.1016/j.synthmet.2005.01.035
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Aromatic monomers can be polymerised using the chloroaluminate room temperature melt obtained by mixing 1:2 ratio of cetyl pyridinium chloride and anhydrous aluminium chloride miscible in all proportions with organic solvents as an electrolyte. The chloroaluminate (AlCl4-) anion generated in this melt having a tetrahedral symmetry with equal bond lengths and bond angles is the dopant to stabilize macrocation generated near the vicinity of anode to yield better conducting and better ordered electronically conducting free standing polymer film. In this communication, we discuss the polymers derived from benzene and pyrrole and their characterization by various techniques. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：306 / 310
页数：5
相关论文
共 50 条
  • [21] Highly conductive proton-conducting electrolyte with a low sintering temperature for electrochemical ammonia synthesis
    Lei, Ze
    Jing, Junmeng
    Pang, Jie
    Hu, Ranyue
    Shi, Xingting
    Yang, Zhibin
    Peng, Suping
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (15) : 8041 - 8051
  • [22] Electrochemical Synthesis of the Functionalized Poly(pyrrole) Conducting Polymers
    Chang, Choo Hwan
    Son, Pyung Soo
    Yang, Ji-Hoon
    Choi, Seong-Ho
    JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2009, 53 (02): : 111 - 117
  • [23] Electrochemical synthesis of ammonia using a proton conducting solid electrolyte and nickel cermet electrode
    Satokawa, Shigeo (satokawa@st.seikei.ac.jp), 2017, Ceramic Society of Japan (125)
  • [24] Electrochemical synthesis of ammonia using a proton conducting solid electrolyte and nickel cermet electrode
    Shimoda, Naohiro
    Kobayashi, Yusuke
    Kimura, Yutaka
    Nakagawa, Go
    Satokawa, Shigeo
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2017, 125 (04) : 252 - 256
  • [25] POLYPYRROLE POLYMER ELECTROLYTE BILAYER COMPOSITES PREPARED BY ELECTROCHEMICAL POLYMERIZATION OF PYRROLE USING ION-CONDUCTING POLYMERS AS A SOLID ELECTROLYTE
    WATANABE, M
    TADANO, K
    SANUI, K
    OGATA, N
    CHEMISTRY LETTERS, 1987, (06) : 1239 - 1242
  • [26] Synthesis and characterization of polyazomethine conducting polymers and oligomers
    El-Shekeil, A. G.
    Hamid, S.-A. M. K.
    Ali, D. A.
    Angewandte Makromolekulare Chemie, (253):
  • [27] Synthesis and characterization of polyazomethine conducting polymers and oligomers
    El-Shekeil, AG
    Hamid, SAMK
    Ali, DA
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1997, 253 : 99 - 110
  • [28] Physicochemical, spectroscopic and electrochemical characterization of magnesium ion-conducting, room temperature, ternary molten electrolytes
    Narayanan, N. S. Venkata
    Raj, B. V. Ashok
    Sampath, S.
    JOURNAL OF POWER SOURCES, 2010, 195 (13) : 4356 - 4364
  • [29] ELECTROCHEMICAL SYNTHESIS AND CHARACTERIZATION OF NEW CONDUCTING POLYHETEROCYCLES
    ALDISSI, M
    WROBLESKI, D
    GOTTFIELD, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 158 - PMSE
  • [30] Conducting Biopolymer Composite Electrolyte Films: Synthesis and Characterization
    Sharma, Prabhakar
    Kumar, Kailash
    Sehrawat, Rajeev
    Banerjee, Diptonil
    Singh, Pramod K.
    Pandey, Shri Prakash
    JOURNAL OF ELECTRONIC MATERIALS, 2024, 53 (07) : 4011 - 4017
12345