Electrochemical synthesis and characterization of conducting polymers using room temperature melt as an electrolyte

被引：7
|
作者：
Geetha, S [1 ]
Trivedi, DC [1 ]
机构：
[1] Cent Electrochem Res Inst, Ctr Conducting Polymers, Karaikkudi 630006, Tamil Nadu, India
来源：
SYNTHETIC METALS | 2005年 / 155卷 / 02期
关键词：
chloroaluminate; room temperature melt; conductivity; polypyrrole; polyparaphenylene;
D O I：
10.1016/j.synthmet.2005.01.035
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Aromatic monomers can be polymerised using the chloroaluminate room temperature melt obtained by mixing 1:2 ratio of cetyl pyridinium chloride and anhydrous aluminium chloride miscible in all proportions with organic solvents as an electrolyte. The chloroaluminate (AlCl4-) anion generated in this melt having a tetrahedral symmetry with equal bond lengths and bond angles is the dopant to stabilize macrocation generated near the vicinity of anode to yield better conducting and better ordered electronically conducting free standing polymer film. In this communication, we discuss the polymers derived from benzene and pyrrole and their characterization by various techniques. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：306 / 310
页数：5
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