Diazidobis[4,4,5,5-tetramethyl-2-(1,3-thiazol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ2O,N]manganese(II)

被引：1
|
作者：
Chang, Jiu Li [1 ]
Gao, Zhi Yong [1 ]
Jiang, Kai [1 ]
机构：
[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453002, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
基金：
中国国家自然科学基金;
关键词：
ALPHA-NITRONYL NITROXIDE; STABLE FREE RADICALS; MAGNETIC-PROPERTIES; IMINO;
D O I：
10.1107/S1600536809000786
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the title compound, [Mn(N-3)(2)-(C10H14N3O2S)(2)], the Mn(II) atom exhibits a roughly octahedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one halfmolecule. The metal center is six- coordinated by two azide anions and by two chelating 4,4,5,5-tetramethyl-2-(1,3-thiazol-2- yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings.
引用
收藏
页码：M181 / U609
页数：9
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