Analysis of residues of prometryne and acetochlor in soil-water system by solid-phase extraction and gas chromatography/mass spectrometry

被引：4
|
作者：
Tan, Wei [1 ,2 ]
Hu, Xiaoxu [1 ,2 ]
Yang, Min [1 ,2 ]
Barrow, Colin J. [3 ]
Yang, Wenrong [3 ,4 ]
Wang, Hongbin [1 ,2 ,3 ,4 ]
机构：
[1] Yunnan Univ Nationalities, State Ethn Affairs Commiss, Key Lab Chem Ethn Med Resources, Sch Chem & Biotechnol, Kunming 650031, Peoples R China
[2] Yunnan Univ Nationalities, Minist Educ, Kunming 650031, Peoples R China
[3] Deakin Univ, Sch Life & Environm Sci, Geelong, Vic 3216, Australia
[4] Univ Sydney, Austrian Ctr Microscopy & Microanal, Sydney, NSW 2006, Australia
来源：
DESALINATION AND WATER TREATMENT | 2014年 / 52卷 / 4-6期
关键词：
Soil; Prometryne; Acetochlor; Solid-phase extraction; Gas chromatography-mass spectrometer; PESTICIDES; MICROEXTRACTION; ADSORPTION; PRODUCTS; ATRAZINE; FOOD;
D O I：
10.1080/19443994.2013.827310
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A highly sensitive and simple analytical method was developed for analyzing the binary mixed pesticides of prometryne and acetochlor in soil-water system by gas chromatography/mass spectrometry (GC/MS). The sample solution was first purified by C-18 solid-phase extraction column, which was leached by acetone. The leachate was enriched to 1.0mL by pressure blowing concentrator and then analyzed by GC/MS. The linear calibration curves were showed in the range of 1-15g/mL with a correlation coefficient of 0.9991. The average recoveries (n=5) were between 95.3 and 115.7%, with relative standard deviations ranged from 1.71 and 7.95%. The limits of detection of Prometryne/Acetochlor were up to 0.06 and 0.17g/mL, respectively. This method provides a reliable approach to examine and evaluate the residues of prometryne and acetochlor in the soil-water system.
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页码：1177 / 1182
页数：6
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