Determination of hydrogen solubility in oxide ceramics by using SIMS analyses

被引：76
|
作者：
Sakai, N
Yamaji, K
Horita, T
Yokokawa, H
Hirata, Y
Sameshima, S
Nigara, Y
Mizusaki, J
机构：
[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan
[2] Kagoshima Univ, Fac Engn, Kagoshima 8900065, Japan
[3] Tohoku Univ, Sci Measurements Res Inst, Aoba Ku, Sendai, Miyagi 9808577, Japan
来源：
SOLID STATE IONICS | 1999年 / 125卷 / 1-4期
关键词：
CeO2; Ce0.8M0.2O1.9;
D O I：
10.1016/S0167-2738(99)00192-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogen solubility in oxide ceramics was evaluated by annealing in D2O-containing atmosphere and subsequent secondary ion mass spectrometry (SIMS). A good proportional relation was obtained between the relative intensity of deuterium ion in SIMS and literature data of hydrogen solubility for YSZ and Sr(Yb)CeO3-delta. The hydrogen solubility in CeO2 and rare-earth doped ceria (Ce0.8M0.2O1.9, M = Y, La, Nd, Sm, Gd, Yb) was evaluated. The hydrogen solubility in ceria dramatically increased by rare earth substitution, and it depended on the lattice parameter of Ce0.8M0.2O1.9. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：325 / 331
页数：7
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