Platinum(II) chloride complexes of linear alkyl-bridged 2,2′-bipyridine/catechol ligands

被引：0
|
作者：
Albrecht, M
Riether, C
Fröhlich, R
机构：
[1] Univ Karlsruhe, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Univ Munster, Inst Organ Chem, D-4400 Munster, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 08期
关键词：
2,2 '-bipyridine; catechol; platinum; sequential ligands;
D O I：
10.1002/(SICI)1521-3749(199908)625:8<1343::AID-ZAAC1343>3.0.CO;2-H
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Platinum(II) chloride can selectively be coordinated to the 2,2'-bipyridine moiety of the alkyl bridged sequential catechol/2,2'-bipyridine ligand 1a-H-2 and of the related ligands 1 a/b-Me-2 and 2. Reaction of (1b-Me-2)PtCl2 with BBr3 produces the platinum(II) complex (1b-H-2)PtCl2 while ether cleavage of the uncoordinated ligand 1b-Me-2 fails. Under basic conditions (1a-H-2)PtCl2 forms polymeric/oligomeric species [(1a)Pt](n) besides traces of the dinuclear complex [(1a)Pt](2).
引用
收藏
页码：1343 / 1348
页数：6
相关论文
共 50 条
  • [21] BIS(2,2'-BIPYRIDINE)(4,4'-DIUNTRIACONTANYL-2,2'-BIPYRIDINE)-RUTHENIUM(II) CHLORIDE AND RELATED HYDROPHOBIC COMPLEXES
    SEDDON, KR
    YOUSIF, YZ
    TRANSITION METAL CHEMISTRY, 1986, 11 (12) : 443 - 446
  • [22] Synthesis and characterization of acyclic and cyclic aza-bridged ligands incorporating 2,2′-bipyridine subunits and their complexes with copper(II), cobalt(II), and nickel(II)
    Mamo, A
    Pappalardo, A
    MOLECULES, 2003, 8 (07) : 521 - 535
  • [23] Structural studies of Ni(II), Zn(II) and Cd(II) complexes with saccharinate and 2,2′-bipyridine ligands
    Johns, CA
    Hossain, GMG
    Malik, KMA
    Haider, SZ
    Romman, UKR
    POLYHEDRON, 2001, 20 (7-8) : 721 - 726
  • [24] Photolysis and Thermolysis of Platinum(IV) 2,2′-Bipyridine Complexes Lead to Identical Platinum(II) DNA Adducts
    Loup, Christophe
    Vallina, Ana Tesouro
    Coppel, Yannick
    Letinois, Ulla
    Nakabayashi, Yasuo
    Meunier, Bernard
    Lippert, Bernhard
    Pratviel, Genevieve
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (37) : 11420 - 11431
  • [25] Free energy correlations of platinum(II) biphenyl complexes containing 2,2′-bipyridine derivatives
    Rillema, D. Paul
    Huang, Wei
    Cruz, Arvin John
    Siam, Khamis
    Base, Derek
    Jehan, Ali
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [26] SCANDIUM THIOCYANATE, NITRATE AND CHLORIDE COMPLEXES WITH 2,2'-BIPYRIDINE
    KOMISSAROVA, LN
    SAS, TM
    EREMIN, YG
    KATOCHKI.VS
    ZHURNAL NEORGANICHESKOI KHIMII, 1971, 16 (12): : 3224 - +
  • [27] BIS(2,2'BIPYRIDINE) RUTHENIUM(II) COMPLEXES
    BROOMHEAD, JA
    ILEPERUMA, O
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (12): : 3181 - 3182
  • [28] 2,2'-BIPYRIDINE COMPLEXES OF ZINC(II) HALIDES
    GHOSH, SN
    INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1969, 5 (10): : 841 - &
  • [29] Effect of Nonchromophoric Ligands on the Spectral Characteristics of Ruthenium(II) (2,2'-Bipyridine)diphosphine Complexes
    A. Yu. Ershov
    S. V. Litke
    A. S. Litke
    T. V. Mezentseva
    Ya. M. Grigor'ev
    G. N. Lyalin
    Russian Journal of General Chemistry, 2002, 72 : 1164 - 1166
  • [30] Effect of nonchromophoric ligands on the spectral characteristics of ruthenium(II) (2,2′-bipyridine)diphosphine complexes
    Ershov, AY
    Litke, SV
    Litke, AS
    Mezentseva, TV
    Grigor'ev, YM
    Lyalin, GN
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (08) : 1164 - 1166
12345