An aqueous manganese-copper battery for large-scale energy storage applications

被引:47
|
作者
Wei, L. [1 ]
Zeng, L. [1 ]
Wu, M. C. [1 ]
Jiang, H. R. [1 ]
Zhao, T. S. [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Mech & Aerosp Engn, HKUST Energy Inst, Kowloon, Clear Water Bay, Hong Kong, Peoples R China
关键词
Mn-Cu battery; Celgard separator; Low cost; Energy storage; REDOX FLOW BATTERY; DRAMATIC PERFORMANCE GAINS; POLYBENZIMIDAZOLE MEMBRANES; FUEL-CELL; ELECTRODE; ZINC; HYDROGEN; DIOXIDE; FELT;
D O I
10.1016/j.jpowsour.2019.03.085
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work reports on a new aqueous battery consisting of copper and manganese redox chemistries in an acid environment. The battery achieves a relatively low material cost due to ubiquitous availability and inexpensive price of copper and manganese salts. It exhibits an equilibrium potential of similar to 1.1 V, and a coulombic efficiency of higher than 94% is obtained at an operating current of 20 mA cm(-2). Cyclic tests confirm that the energy efficiency maintains similar to 79% with no observable decay at 10 mA cm(-2) over 100 cycles. Possessing other advantages such as ease of scalability and capable of using an inexpensive separator, the battery offers a promising solution for large-scale energy storage applications.
引用
收藏
页码:203 / 210
页数:8
相关论文
共 50 条
  • [41] A comprehensive review on large-scale photovoltaic system with applications of electrical energy storage
    Lai, Chun Sing
    Jia, Youwei
    Lai, Loi Lei
    Xu, Zhao
    McCulloch, Malcolm D.
    Wong, Kit Po
    RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2017, 78 : 439 - 451
  • [42] A review of large-scale electrical energy storage
    Hameer, Sameer
    van Niekerk, Johannes L.
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2015, 39 (09) : 1179 - 1195
  • [43] LARGE-SCALE ELECTRICAL ENERGY-STORAGE
    DAVIDSON, BJ
    GLENDENNING, I
    HARMAN, RD
    HART, AB
    MADDOCK, BJ
    MOFFITT, RD
    NEWMAN, VG
    SMITH, TF
    WORTHINGTON, PJ
    WRIGHT, JK
    IEE PROCEEDINGS-A-SCIENCE MEASUREMENT AND TECHNOLOGY, 1980, 127 (06): : 345 - 385
  • [44] Comparison of large-scale energy storage technologies
    Klumpp, Florian
    PROCEEDINGS OF THE INSTITUTION OF CIVIL ENGINEERS-ENERGY, 2016, 169 (04) : 148 - 160
  • [45] Large-Scale Energy Storage for Carbon Neutrality
    Liu, Ke
    Ding, Yulong
    ENGINEERING, 2023, 29 : 1 - 1
  • [46] APPROACHES TO LARGE-SCALE ENERGY-STORAGE
    POST, RF
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1975, 20 (01): : 53 - 53
  • [47] A novel aqueous sodium-manganese battery system for energy storage
    Feng, Yazhi
    Zhang, Qiu
    Liu, Shuang
    Liu, Jian
    Tao, Zhanliang
    Chen, Jun
    JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (14) : 8122 - 8128
  • [48] Cost evaluation and sensitivity analysis of the alkaline zinc-iron flow battery system for large-scale energy storage applications
    Chen, Ziqi
    Liu, Yongfu
    Yu, Wentao
    He, Qijiao
    Ni, Meng
    Yang, Shuquan
    Zhang, Shuanglin
    Tan, Peng
    JOURNAL OF ENERGY STORAGE, 2021, 44
  • [49] A comparative overview of large-scale battery systems for electricity storage
    Poullikkas, Andreas
    RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2013, 27 : 778 - 788
  • [50] Fast equalization of lithium battery energy storage system based on large-scale global optimization
    An, Qing
    Li, Yaqiong
    Zhang, Xia
    Rao, Lang
    JOURNAL OF POWER SOURCES, 2025, 627