Adsorption of Paracetamol in Hospital Wastewater Through Activated Carbon Filters

被引:51
|
作者
Macias-Garcia, Antonio [1 ]
Garcia-Sanz-Calcedo, Justo [2 ]
Pablo Carrasco-Amador, Juan [2 ]
Segura-Cruz, Raul [3 ]
机构
[1] Univ Extremadura, Dept Mech Energet & Mat Engn, Elvas Ave S-N, Badajoz 06006, Spain
[2] Univ Extremadura, Dept Graph Express, Elvas Ave S-N, Badajoz 06006, Spain
[3] Autonomous Univ State Mexico, Rase Prod Project, Saturno St 207, Metepec 52159, Mexico
关键词
wastewater hospital; healthcare engineering; healthcare projects; ORGANIC MICROPOLLUTANT; AQUEOUS-SOLUTIONS; EMERGING CONTAMINANTS; METHYL-ORANGE; REMOVAL; KINETICS; ISOTHERM; SURFACE; PHARMACEUTICALS; ENVIRONMENT;
D O I
10.3390/su11092672
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In recent years, pharmaceutical products have been causing a serious environmental problem in hospital wastewater and water purification plants. The elimination of these pollutants is difficult due to their resistance to biological degradation. Paracetamol has been detected in higher concentrations in hospital wastewater than in other buildings. Activated carbons are a good material for removing paracetamol from hospital wastewater. One of the starting materials to obtain activated carbons is kenaf, which is an easy plant to cultivate. To study the elimination of paracetamol from hospital wastewater by activated carbon, the textural and chemical characterization of activated carbon, as well as the kinetic study and the analysis of the paracetamol adsorption mechanism by the adsorbent, have been carried out. The activated carbon samples studied are micro-mesoporous, with high specific surface values. The chemical composition with presence of oxygen groups favours the adsorption process. The adsorption kinetics were adjusted to a pseudo-second order model. The adsorption mechanism followed the intraparticular diffusion model, carried out in two stages: a fast first stage on the surface of the adsorbent and a slow one inside the pore. Based on the kinetic study, the use of this type of carbon is a good application for the removal of paracetamol from hospital wastewater.
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页数:11
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