Unravelling the water adsorption in a robust iron carboxylate metal-organic framework

被引:13
|
作者
Lenzen, Dirk [1 ]
Eggebrecht, Jakob G. [2 ]
Mileo, Paulo G. M. [3 ]
Froehlich, Dominik [4 ]
Henninger, Stefan [4 ]
Atzori, Cesare [5 ,6 ,7 ]
Bonino, Francesca [5 ,6 ]
Lieb, Alexandra [2 ]
Maurin, Guillaume [3 ]
Stock, Norbert [1 ]
机构
[1] Christian Albrechts Univ Kiel, Inst Inorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
[2] Otto von Guericke Univ, Inst Chem, Univ Pl 2, D-39106 Magdeburg, Germany
[3] Univ Montpellier, ENSCM, CNRS, ICGM, Montpellier, France
[4] Fraunhofer Inst Solare Energiesyst ISE, Dept Heating & Cooling Technol, Grp Sorpt Mat, Heidenhofstr 2, D-79110 Freiburg, Germany
[5] Univ Torino, NIS & INSTM Reference Ctr, Dept Chem, Via G Quarello 15, I-10135 Turin, Italy
[6] Univ Torino, NIS & INSTM Reference Ctr, Dept Chem, Via P Giuria 7, I-10125 Turin, Italy
[7] European Synchrotron Radiat Facil, 71 Ave Martyrs,CS 40220, F-38043 Grenoble 9, France
关键词
HEAT TRANSFORMATION; SORPTION MATERIALS; ADSORBENTS; PUMPS;
D O I
10.1039/d0cc03489d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Fe-MOF was obtained from aqueous solution in high yield under reflux. The water sorption properties were studied by powder X-ray diffraction, volumetric and gravimetric sorption experiments and molecular simulations. The subsequent filling of hydrophobic and hydrophilic pores as well as the stability of the material are demonstrated.
引用
收藏
页码:9628 / 9631
页数:4
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