Impact of direct butane microtubular solid oxide fuel cells

被引：36
|
作者：
Sumi, Hirofumi [1 ]
Yamaguchi, Toshiaki [1 ]
Hamamoto, Koichi [1 ]
Suzuki, Toshio [1 ]
Fujishiro, Yoshinobu [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Adv Mfg Res Inst, Nagoya, Aichi 4638560, Japan
来源：
JOURNAL OF POWER SOURCES | 2012年 / 220卷
关键词：
Solid oxide fuel cell (SOFC); Ni-based anodes; Ceria; Hydrocarbon; Carbon deposition; SCANDIA-STABILIZED ZIRCONIA; SOFC ANODES; CARBON DEPOSITION; HYDROCARBON FUELS; DIRECT-OXIDATION; METHANE; STEAM; PERFORMANCE; NI;
D O I：
10.1016/j.jpowsour.2012.07.106
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We investigated direct butane power generation for microtubular solid oxide fuel cells with a diameter of less than 2 mm. Conventional Ni-stabilized zirconia anodes deteriorated rapidly over a period of 3-4 h at 610 degrees C and a low steam/carbon (S/C) ratio of 0.044 in butane due to a large amount of carbon deposition. For the Ni-Gd doped ceria (Ni-GDC) anode, the power could be generated continuously for more than 24 h at 610 degrees C and S/C = 0.044 in butane. The rate of carbon deposition for the Ni-GDC was slower than that for the Ni-stabilized zirconia at 610 degrees C. Ceria can be reduced from Ce4+ to Ce3+, which causes the suppression of carbon deposition on the Ni-GDC anode in butane at low humidity. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：74 / 78
页数：5
相关论文
共 50 条
  • [21] Modelling of microtubular solid oxide fuel cells. Overview of the SUAV project
    Pianko-Oprych, Paulina
    Jaworski, Zdzislaw
    PRZEMYSL CHEMICZNY, 2013, 92 (01): : 51 - 54
  • [22] Microtubular solid oxide fuel cells with lanthanum strontium manganite infiltrated cathodes
    Laguna-Bercero, M. A.
    Hanifi, A. R.
    Etsell, T. H.
    Sarkar, P.
    Orera, V. M.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (15) : 5469 - 5474
  • [23] Highly stable microtubular cells for portable solid oxide fuel cell applications
    Monzon, H.
    Laguna-Bercero, M. A.
    ELECTROCHIMICA ACTA, 2016, 222 : 1622 - 1627
  • [24] Microtubular solid-oxide fuel cells for low-temperature operation
    Toshio Suzuki
    Toshiaki Yamaguchi
    Hirofumi Sumi
    Koichi Hamamoto
    Yoshinobu Fujishiro
    MRS Bulletin, 2014, 39 : 805 - 809
  • [25] Direct hydrocarbon solid oxide fuel cells
    McIntosh, S
    Gorte, RJ
    CHEMICAL REVIEWS, 2004, 104 (10) : 4845 - 4865
  • [26] Impact of lamination conditions on microtubular solid oxide fuel cells fabricated by tape casting coupled with isostatic pressing
    Altan, Tolga
    Timurkutluk, Cigdem
    Timurkutluk, Bora
    JOURNAL OF POWER SOURCES, 2022, 532
  • [27] The impact of physicochemical properties of coal on direct carbon solid oxide fuel cells
    Dudek, Magdalena
    Skrzypkiewicz, Marek
    Moskala, Norbert
    Grzywacz, Przemyslaw
    Sitarz, Maciej
    Lubarska-Radziejewska, Iwona
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (41) : 18872 - 18883
  • [28] Microtubular Solid Oxide Fuel Elements: Development and Testing
    Bagishev, A. S.
    Niftalieva, N., V
    Kovalevi, I., V
    Voloshin, B. V.
    Popov, M. P.
    Lyskov, N., V
    Levchenko, E. A.
    Gvozdkov, I. A.
    Sinitsyn, V. V.
    Sivak, A., V
    Nemudry, A. P.
    CHEMISTRY FOR SUSTAINABLE DEVELOPMENT, 2019, 27 (03): : 246 - 250
  • [29] Direct operation of solid oxide fuel cells with methane fuel
    Lin, YB
    Zhan, ZL
    Liu, J
    Barnett, SA
    SOLID STATE IONICS, 2005, 176 (23-24) : 1827 - 1835
  • [30] Preparation and performance of a nano-honeycomb cathode for microtubular solid oxide fuel cells
    Yao, Yue
    Wang, Chenpeng
    Ma, Yue
    Ye, Hao
    Liu, Yinglong
    Liu, Jiawei
    Zhao, Xiaobo
    Tao, Tao
    Yao, Yingbang
    Lu, Shengguo
    Yang, Huazheng
    Liang, Bo
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (13) : 5229 - 5236
12345