Structure-directing role of immobilized polyoxometalates in the synthesis of porphyrinic Zr-based metal-organic frameworks

被引：17

作者：

Duguet, Mathis ^{[1
,2
]}

Lemarchand, Alex ^{[2
]}

Benseghir, Youven ^{[1
,2
]}

Mialane, Pierre ^{[1
]}

Gomez-Mingot, Maria ^{[2
]}

Roch-Marchal, Catherine ^{[1
]}

Haouas, Mohamed ^{[1
]}

Fontecave, Marc ^{[2
]}

Mellot-Draznieks, Caroline ^{[2
]}

Sassoye, Capucine ^{[3
]}

Dolbecq, Anne ^{[1
]}

机构：

[1] Univ Paris Saclay, UVSQ, CNRS, UMR 8180,Inst Lavoisier Versailles, F-78035 Versailles, France

[2] Sorbonne Univ, Lab Chim Proc Biol, UMR CNRS 8229, Coll France,PSL Res Univ, 11 Pl Marcelin Berthelot, F-75231 Paris 05, France

[3] Sorbonne Univ, UMR 7574, Coll France, Lab Chim Matiere Condensie Paris, 4 Pl Jussieu, F-75252 Paris 05, France

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 70期

关键词：

DIFFRACTION;

D O I：

10.1039/d0cc04283h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We evidence the structure-directing role of the PW(12)O(40)(3-)polyoxometalate in porphyrinic MOF synthesis whereby it promotes the formation of the kinetic topology. Its immobilization into the MOF is successfully achieved at a high temperature yielding the kinetic MOF-525/PCN-224 phases, while prohibiting the formation of the thermodynamic MOF-545 product. A combined experimental/theoretical approach uses differential PDF and DFT calculations along with solid-state NMR to show the structural integrity of the POM and its location next to the Zr-based nodes.

引用

页码：10143 / 10146

页数：4

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