Low-temperature heat capacity and the standard molar enthalpy of formation of compound chromium(III) tri(pyrazine-2-carboxylate)

Low-temperature heat capacities of the coordination compound, chromium(III) tri(pyrazine-2-carboxylate), formulated as Cr(pyza)(3) (pyza = pyrazine-2-carboxylate), were measured by a precision automated adiabatic calorimeter over the temperature range of 78-400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial equation, the fitted heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated at the interval of 5 K. In accordance with a reasonable thermochemical cycle designed, the standard molar enthalpy of formation of the title complex was determined to be -1207.86 +/- 3.39 kJ mol(-1) by an isoperibol solution-reaction calorimeter. (C) 2012 Elsevier B.V. All rights reserved.