Synthesis of Six-Membered N-Heterocycles Using Ruthenium Catalysts

被引:33
|
作者
Kaur, Navjeet [1 ]
机构
[1] Banasthali Vidyapith, Dept Chem, Banasthali 304022, Rajasthan, India
关键词
Ruthenium; Catalysis; Nitrogen heterocycles; Grubs catalyst; RCM; Asymmetric synthesis; MICROWAVE-ASSISTED SYNTHESIS; RING-CLOSING-METATHESIS; DIVERSELY FUNCTIONALIZED PYRROLIZIDINES; FUSED BICYCLIC IMIDAZOLES; OLEFIN-METATHESIS; ASYMMETRIC-SYNTHESIS; 2+2+2 CYCLOADDITION; DIASTEREOSELECTIVE SYNTHESIS; ENYNE METATHESIS; NITROGEN-HETEROCYCLES;
D O I
10.1007/s10562-019-02746-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A wide variety of biological activities are possessed by nitrogen, oxygen, and sulfur containing heterocycles and many methods are explored for the preparation of these heterocyclic compounds. Metal catalysts worked with high activity in organic reactions. The synthesis of heterocycles with the help of metal catalysts became very important in organic synthesis. New protocols have been investigated for the synthesis of heterocycles in the last decades. This article mainly focused on the synthesis of six-membered N-heterocylces in the presence of ruthenium catalyst. [GRAPHICS] .
引用
收藏
页码:1513 / 1559
页数:47
相关论文
共 50 条
  • [21] Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles
    Lu, Zhan
    Stahl, Shannon S.
    ORGANIC LETTERS, 2012, 14 (05) : 1234 - 1237
  • [22] Hydrogen-bond basicity pKHB scale of six-membered aromatic N-heterocycles
    Berthelot, M
    Laurence, C
    Safar, M
    Besseau, F
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (02): : 283 - 290
  • [23] An Organocatalytic Approach to the Synthesis of Six-Membered Heterocycles
    Gasperi, Tecla
    Punzi, Pasqualina
    Migliorini, Antonella
    Tofani, Daniela
    CURRENT ORGANIC CHEMISTRY, 2011, 15 (13) : 2098 - 2146
  • [24] Six-membered heterocycles: their synthesis and bio applications
    Shiri, Pezhman
    Roosta, Atefeh
    Ramezanpour, Sorour
    Amani, Ali Mohammad
    FRONTIERS IN CHEMISTRY, 2023, 11
  • [25] Photochemical Multicomponent Synthesis of Six-Membered Heterocycles
    Borah, Biplob
    Patat, Mihir
    Raju Chowhan, L.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2025,
  • [26] Metal-free multicomponent reactions: a benign access to monocyclic six-membered N-heterocycles
    Preeti
    Singh, Krishna Nand
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (12) : 2622 - 2657
  • [27] Directing group-assisted selective C-H activation of six-membered N-heterocycles and benzo-fused N-heterocycles
    Mohanty, Smruti Ranjan
    Prusty, Namrata
    Nanda, Tanmayee
    Mahulkar, Pranav Shridhar
    Ravikumar, Ponneri C.
    ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (02) : 540 - 575
  • [28] Triplet states of six-membered N-heterocycles: Phosphorescence of pyrazine and its two conjugate acids
    Ghabowska, A.
    Pakula, B.
    CHEMICAL PHYSICS LETTERS, 1967, 1 (09) : 369 - 372
  • [29] Synthesis of five-membered N-heterocycles using Rh based metal catalysts
    Kaur, Navjeet
    Ahlawat, Neha
    Bhardwaj, Pranshu
    Verma, Yamini
    Grewal, Pooja
    Jangid, Nirmala Kumari
    SYNTHETIC COMMUNICATIONS, 2020, 50 (02) : 137 - 160
  • [30] Metal catalysts: applications in higher-membered N-heterocycles synthesis
    Navjeet Kaur
    Journal of the Iranian Chemical Society, 2015, 12 : 9 - 45