Synthesis, characterization and stability of bismaleimides containing ester groups in the backbone

被引：16

作者：

Sava, M

Gaina, C

Gaina, V

Chiriac, C

Stoleriu, A

机构：

[1] Petru Poni Inst. Macromolec. Chem., RO-6600 IASI, Aleea Gr.Ghica

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1997年 / A34卷 / 08期

关键词：

RESINS;

D O I：

10.1080/10601329708011060

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new series of bismaleimides containing ester groups in the backbone were synthesized from maleimido benzoic acid via its acid chloride with 4,4'-(hexa-fluoroisopropilidene)diphenol, 2,7-dihydroxynaphtalin, 1,3-dihydroxy-benzene and 4-hydroxyphenyl sulfone by simple condensation reaction. The monomers are characterized by IR, H-1-NMR and elemental analysis. DSC studies of these bismaleimides indicated a curing exotherm in the temperature range 260-306 degrees C with polymerization heat 92.9-139.6 J/g. Thermogravimetric analysis of the monomers showed high thermal stability for all bismaleimides.

引用

页码：1505 / 1514

页数：10

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