Bis(N,N-dimethylformamide-κO)-bis(1-methylimidazole-2-carbaldehyde oximato-κ2N,O)manganese(III) perchlorate

被引：0
|
作者：
Wang, Feng [1 ]
Zhang, Jianming [1 ]
Wang, Qirong [2 ]
Huang, Shiying [3 ]
机构：
[1] Cent China Normal Univ, Coll Chem, Wuhan 430079, Hubei, Peoples R China
[2] Xiaogan Univ, Sch Chem & Mat Sci, Xiaogan 432000, Hubei, Peoples R China
[3] Hubei Polytech Inst, Xiaogan 432000, Hubei, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808034016
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Mn(C5H6N3O)(2)(C3H7NO)]ClO4, the Mn-III atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octahedral coordination geometry, formed by two N atoms and two O atoms from two 1-methylimidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethylformamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C-H center dot center dot center dot O hydrogen-bonding interactions.
引用
收藏
页码：M1462 / U1094
页数：12
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