Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes

被引:1
|
作者
Sun Qing-Rui [1 ,2 ]
Chen Zi-Xian [1 ,3 ]
Li Shan [1 ]
Wu Yong-Ming [1 ]
Tian Wei-Sheng [1 ]
机构
[1] Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
[2] Shanghai Normal Univ, Life & Environm Sci Coll, Shanghai 200234, Peoples R China
[3] Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
1,3-dipolar cycloaddition; fluoroalkylazide; fluoroalkylated triazoline; fluoroalkylated pyrazoline;
D O I
10.1002/cjoc.200890339
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 1,3-dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.
引用
收藏
页码:1887 / 1892
页数:6
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