Characterization of new sulfur and selenium-based glasses containing lead iodide

被引：7
|
作者：
Troles, J [1 ]
Smektala, F [1 ]
Jestin, Y [1 ]
Begoin, L [1 ]
Danto, S [1 ]
Guignard, M [1 ]
机构：
[1] Univ Rennes 1, CNRS, UMR 6512, Lab Verres & Ceram, F-35042 Rennes, France
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2006年 / 352卷 / 03期
关键词：
glass formation; glass transition; chalcogenides; absorption; thermal properties;
D O I：
10.1016/j.jnoncrysol.2005.11.034
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The aim of this work is to investigate and qualify vitreous regions in new chalcogenide systems containing highly polarizable elements like S, Se, As, Sb, Bi, Pb and I. The sulfur based system, As2S3-Sb2S3-Bi2S3-PbI2, as well as the selenium containing glasses As2Se3Sb2Se3-PbI2 have been studied. Large vitreous regions have been defined in the both systems: sulfur and selenium. Indeed, several glass compositions can accept in the vitreous network a molar concentration near 50% of PbI2. Physical properties such as glass transition temperature, crystallization temperature, optical transmission, band-gap wavelength have been measured versus glassy compositions. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：248 / 254
页数：7
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