The Inhibition Effect of 2-amino-4-chlorobenzothiazole on X65 Steel Corrosion in H2SO4 Solution

被引:2
|
作者
Chen, Shujun [1 ]
Chen, Siyi [1 ]
Zhao, Huajun [1 ]
Wang, Hao [1 ]
Wen, Pushan [1 ]
Li, Hao [2 ]
机构
[1] Zunyi Normal Univ, Sch Chem & Chem Engn, Zunyi 563006, Guizhou, Peoples R China
[2] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China
来源
基金
美国国家科学基金会;
关键词
Corrosion inhibitor; X65; steel; potentiodynamic polarization curve; Quantum chemical calculations; Langmuir adsorption; COPPER CORROSION; SULFURIC-ACID; INDAZOLE DERIVATIVES; CARBON-STEEL; MECHANISM; PERFORMANCE; PROTECTION; SODIUM;
D O I
10.20964/2020.06.37
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, we study 2-amino-4-chlorobenzothiazole (ACBT) as a corrosion inhibitor for X65 steel in H2SO4 medium. The corrosion inhibition performance of ACBT for X65 steel has been studied using electrochemical methods, surface morphology analysis and theoretical calculations. Electrochemical experiment data indicated ACBT belongs to mixed-type corrosion inhibitor. When the concentration of ACBT is 5 mM at 298 K, its corrosion inhibition efficiency is close to 90%. The potentiodynamic polarization curve shows that the inhibition effect of ACBT on the cathodic reaction is significantly greater than that of the anodic reaction. SEM morphology analysis strongly proves the corrosion inhibition performance of ACBT. Quantum chemical calculations and molecular dynamics simulations have revealed the corrosion inhibition properties of ACBT. The adsorption of ACBT on the surface of X65 steel conforms to the Langmuir adsorption isothermal model.
引用
收藏
页码:5208 / 5219
页数:12
相关论文
共 50 条
  • [31] Effect of Piperidin-4-ones on the Corrosion Inhibition of Mild Steel in 1 N H2SO4
    Xavier, Glory Tharial
    Thirumalairaj, Brindha
    Jaganathan, Mallika
    INTERNATIONAL JOURNAL OF CORROSION, 2015, 2015
  • [32] Effect of PgTPhPBr on the electrochemical and corrosion behaviour of 304 stainless steel in H2SO4 solution
    A.A. Hermas
    M.S. Morad
    M.H. Wahdan
    Journal of Applied Electrochemistry, 2004, 34 : 95 - 102
  • [33] Thioamide Compounds as Corrosion Inhibitors for Stainless Steel in H2SO4 Solution
    Hosseini, S. M. A.
    Salari, M.
    Motlagh, M. Ghanei
    CORROSION, 2010, 66 (11)
  • [34] The inhibition of mild steel corrosion in 0.5 M H2SO4 solution by radish leaf extract
    Li, Dongyi
    Zhang, Panpan
    Guo, Xinyu
    Zhao, Xiaowei
    Xu, Ying
    RSC ADVANCES, 2019, 9 (70) : 40997 - 41009
  • [35] Corrosion inhibition of mild steel by expired pyridoxine hydrochloride in 0.5 M H2SO4 solution
    Sheetal
    Thakur, Sanjeeve
    Singh, Ashish Kumar
    INORGANIC CHEMISTRY COMMUNICATIONS, 2024, 166
  • [36] Corrosion inhibition of carbon steel in 1 M H2SO4 solution by Thapsia villosa extracts
    Kalla, A.
    Benahmed, M.
    Djeddi, N.
    Akkal, S.
    Laouer, H.
    INTERNATIONAL JOURNAL OF INDUSTRIAL CHEMISTRY, 2016, 7 (04): : 419 - 429
  • [37] Corrosion inhibition and adsorption behaviour of 4-aminoantipyrine on mild steel in H2SO4
    El Rehim, SSA
    Ibrahim, MAM
    Khaled, KF
    CORROSION PREVENTION & CONTROL, 1999, 46 (06): : 157 - 162
  • [38] Corrosion inhibition and adsorption behaviour of 4-aminoantipyrine on mild steel in H2SO4
    Abd El Rehim, Sayed S.
    Ibrahim, Magdy A. M.
    Khaled, Khaled F.
    Corrosion Prevention and Control, 1999, 46 (06): : 157 - 162
  • [39] Adsorption Behavior and Corrosion Inhibition of EPP for Q235 Steel in H2SO4 Solution
    Zou, Like
    Lai, Chuan
    Xie, Bin
    Yang, Xue
    Xiang, Zhen
    Zeng, Ni
    Huang, Chun
    Wang, Yanmei
    APPLICATIONS OF ENGINEERING MATERIALS, PTS 1-4, 2011, 287-290 : 2923 - +
  • [40] Adsorption and inhibition effect of two aminopyrimidine derivatives on steel surface in H2SO4 solution
    Li, Xianghong
    Xie, Xiaoguang
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (06) : 3033 - 3045